The fabrication and pyroelectric coefficient of Pb(Zr 0.3 Ti 0.7 )O 3 (PZT) nanorod array on Nb:SrTiO 3 (NSTO) substrates were reported. XRD and TEM revealed that PZT nanorods were (001) orientation single crystalline. Dense PZT nanorod array were synthesized on NSTO using optimal 0.8 g/L poly(vinyl alcohol) (PVA) and 3.2 g/L poly(acrylate acid) (PAA). Maximum pyroelectric coefficient, 5.8 ' 10 %9 C/(cm 2 &K), was measured for samples synthesized at 230 °C and poled under 5 V. The single crystalline PZT nanorod array material has potential application in small spatial (1-10 µm) infrared detectors, benefiting to achieve distinguished detector performances.