A new
approach to develop novel hollow urchinlike copper oxide
(CuO) microspheres by the hydrothermal method was reported, and zwitterionic
alkyldimethylbetaine (BS) surfactants were employed as templates in
the classic copper–ammonia complex systems. Effects of numerous
environmental factors on the morphology of CuO particles were studied
systematically, in which the concentration and structure of BS predominantly
affected the developed CuO materials. It was noticed that hollow urchinlike
CuO microspheres were generally formed in the presence of BS regardless
of the reaction temperature and time and the source of copper ions.
Generally speaking, high concentrations of BS and BS with longer chain
length strongly favored the formation of hollow urchinlike CuO microspheres.
The microstructures of synthesized CuO particles were studied in detail,
and the corresponding formation mechanism of hollow urchinlike CuO
microspheres was also proposed based on the selective adsorption of
BS on the particular crystal facets of CuO crystals. Moreover, hollow
urchinlike CuO microspheres showed excellent performance in the lithium-ion
batteries as anode materials with a reversible capability of 511 mA
h·g
–1
at 0.1 C after 40 charge–discharge
cycles, which was one of the best values of CuO materials reported
in this field.