This paper concerns the non-isentropic Euler-Maxwell equations for plasmas with short momentum relaxation time. With the help of the Maxwell-type iteration, it is obtained that, as the relaxation time tends to zero, periodic initial-value problem of certain scaled non-isentropic Euler-Maxwell equations has unique smooth solutions existing in the time interval where the corresponding classical drift-diffusion model has smooth solutions. Meanwhile, we justify a formal derivation of the corresponding drift-diffusion model from the non-isentropic Euler-Maxwell equations.