High-spin states in the odd-odd 174 Re have been investigated via the 152 Sm( 27 Al, 5nγ ) 174 Re reaction with the help of excitation function, x-γ , and γ -γ coincidence measurements. Five rotational bands have been observed and their configurations were assigned based on alignments, band crossing frequencies, electromagnetic properties, and the estimated bandhead excitation energies. Low-spin signature inversion has been identified in the two-quasiparticle bands built on πh 11/2 ⊗ νi 13/2 , πh 9/2 ⊗ νi 13/2 , and π 1/2 − [541] ⊗ ν5/2 − [512] configurations. E2 interband transitions were analyzed with band-mixing calculations giving information on shapes and shape driving effects for the bands of interest.