2020
DOI: 10.1016/j.jechem.2020.01.014
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High performance room temperature all-solid-state Na-Se S battery with Na3SbS4–coated cathode via aqueous solution

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Cited by 18 publications
(6 citation statements)
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“…Employing alloy anodes such as Li–Sn, Li–In, and Na–Sn or passivating the metal anode surface with electronically insulating layers can reduce interfacial degradation. ,,, For example, Ceder et al employed surface hydration to stabilize the SSE–metal interface, which was achieved by exposing the Na 3 SbS 4 electrolyte pellet to ambient air . A concern with using alloy anodes rather than plating/stripping anodes is the reduction in the operating voltage window of the full cell, as well as the degradation of the alloy itself due to the ongoing volume changes.…”
Section: Interlayers and Artificial Sei/cei Layers For Metal–sulfur S...mentioning
confidence: 99%
“…Employing alloy anodes such as Li–Sn, Li–In, and Na–Sn or passivating the metal anode surface with electronically insulating layers can reduce interfacial degradation. ,,, For example, Ceder et al employed surface hydration to stabilize the SSE–metal interface, which was achieved by exposing the Na 3 SbS 4 electrolyte pellet to ambient air . A concern with using alloy anodes rather than plating/stripping anodes is the reduction in the operating voltage window of the full cell, as well as the degradation of the alloy itself due to the ongoing volume changes.…”
Section: Interlayers and Artificial Sei/cei Layers For Metal–sulfur S...mentioning
confidence: 99%
“…2b and S3 †). This value is even higher than the room temperature of some solid electrolytes, 59,60 providing the possibility to construct an all-solid-state battery that enables excellent performances under low operating temperatures. The activation energies of both samples can be deduced based on the temperature-dependent Li-ion conductivities.…”
Section: Resultsmentioning
confidence: 97%
“…19–22 Moreover, the dissolution and shuttle phenomena of the soluble intermediate Na polyselenides (SPSs) cause the loss of active material, leading to capacity decay. 23–25 In addition, the sodiation/desodiation process at the Se cathode is sluggish, which limits the charge and discharge ability of the electrode at a high current density, and is beneficial for the shuttle effect of the soluble SPSs. 26–29 Considering the anode processes, the infinite volume change of Na during charge and discharge leads to low coulombic efficiency (CE) and capacity decay.…”
Section: Introductionmentioning
confidence: 99%