This study presents a hybrid photovoltaic (PV) solar cell consisting of zinc phthalocyanine (ZnPc) on nanoporous gallium arsenide (GaAs) substrates (NPGSs). NPGSs with a low reflectivity are prepared by metal-assisted nanoscale lithography. Au nanoparticles (GNPs) are introduced into the nanoporous structure in organic/inorganic hybrid solar cells to enhance the perfornance of photovoltaic devices. The optimal measured parameters of the PV cell with the ITO/ZnPc + I2 + PMMA (ZIP)/GNPs/NPGS/In structure are Jsc, Voc, fill factor (FF), and power convert efficiency (PCE), which have values of 2.48 mA/cm2, 0.55 V, 0.197, and 2.69%, respectively, under irradiation by a 100 W xenon lamp.