High-Pressure Thermal Hydrogenolysis of Hydrocarbons

Brooks, Claudine

doi:10.1021/i360024a008

Search citation statements

Order By: Relevance

Paper Sections

Select...

Cycloparaffins1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1973

2002

Publication Types

Select...

Article5

Relationship

Self Cite0

Independent5

Authors

Journals

Cited by 6 publications

(1 citation statement)

References 6 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The role of hydrogen in suppressing olefin formation and enhancing paraffin cracking as was found by Brooks (1967) is evident in Figures 3-5. Furthermore, increased hydrogen concentration causes aromatics hydrogenation and accelerates the conversion of naphthenes in agreement with the experimental results of Yamada and Amano (1983).…”

Section: Cycloparaffinsmentioning

confidence: 66%

Comparison of lumped and molecular modeling of hydropyrolysis

Liguras¹,

Allen²

1992

Ind. Eng. Chem. Res.

View full text Add to dashboard Cite

Section: Cycloparaffinsmentioning

confidence: 66%

Comparison of lumped and molecular modeling of hydropyrolysis

Liguras¹,

Allen²

1992

Ind. Eng. Chem. Res.

View full text Add to dashboard Cite

Kinetics and mechanism of primary cracking reactions in thermal high pressure hydrogenolysis of tetralin and indan. Part I

Penninger

Slotboom

1973

Recl. Trav. Chim. Pays‐Bas

View full text Add to dashboard Cite

Kinetics of the primary cracking reactions occurring in the high pressure thermal hydrogenolysis of 1, 2, 3, 4-tetrahydronaphthalene (tetralin) and hydrindene (indan) were studied in a flow reactor at temperatures from 4 6 8 to 548C, total pressures from 10 to 160 atm. and molar ratios of hydrogen-tohydrocarbon from 2 to 100.As primary cracking products from tetralin were identified n-butylbenzene, styrene, ethylene, I-methylindan and o-propyltoluene.From indan were obtained n-propylbenzene, toluene, ethylene, o-ethyltoluene, o-xylene and methane.Chain mechanisms are proposed for the reactions leading to these primary products.The theoretical rate equations derived from these are in good agreement with experimental results. IatroductionThe present publication deals with results of the first part of our experiments on hydrocracking of poly-aromatic hydrocarbons. Hydrocracking meets growing interest from the petroleum industry as a process for converting high molecular oil fractions into a wide range of low boiling components. In the field of thermal hydrocracking extensive work has been published on thermal hydrodealkylation of toluene and xylenesl-'. Our work was strongly motivated by the fact that minor Present address:

show abstract

Compound class modeling of hydropyrolysis

Parnas

Allen

1988

Chemical Engineering Science

View full text Add to dashboard Cite

High-Pressure Thermal Hydrogenolysis of Hydrocarbons

Cited by 6 publications

References 6 publications

Comparison of lumped and molecular modeling of hydropyrolysis

Comparison of lumped and molecular modeling of hydropyrolysis

Kinetics and mechanism of primary cracking reactions in thermal high pressure hydrogenolysis of tetralin and indan. Part I

Compound class modeling of hydropyrolysis

Contact Info

Product

Resources

About