A new measurement of the branching ratio, R e/µ = Γ(π + → e + ν + π + → e + νγ)/Γ(π + → µ + ν + π + → µ + νγ), resulted in R exp e/µ = (1.2344 ± 0.0023(stat) ± 0.0019(syst)) × 10 −4 . This is in agreement with the standard model prediction and improves the test of electron-muon universality to the level of 0.1 %.PACS numbers: 13.20. Cz, 14.40.Be, 14.60.St, The standard model (SM) assumes equal electro-weak couplings of the three lepton generations, a hypothesis known as lepton universality which is studied in high precision measurements of π, K, τ, B, and W decays. A recent measurement of, where l represents e or µ, hinted at a possible violation of e-µ universality in second order weak interactions that involve neutral and charged currents. The branching ratio of pion decays, R e/µ = Γ(π → eν(γ))/Γ(π → µν(γ)), where (γ) indicates inclusion of associated radiative decays, has been calculated in the SM with extraordinary precision to be R [5], has provided one of the best tests of e-µ universality in weak interactions for the charged current, at the 0.2 % level giving sensitivity to new physics beyond the SM up to mass scales of O(500) TeV [3]. Examples of new physics probed include R-parity violating SUSY [6], extra leptons [7] and leptoquarks [8]. In this paper, we present the first results from the PIENU experiment, which improve on the precision of R exp e/µ and the test of e-µ universality.The branching ratio R e/µ is obtained from the ratio of positron yields from the π + → e + ν(γ) decay (total positron energy E e + = 69.8 MeV) and the π + → µ + ν(γ) decay followed by the µ + → e + νν(γ) decay (π + → µ + → e + , E e + = 0.5 − 52.8 MeV) using pions at rest. Figure 1 shows a schematic view of the apparatus [9] in which a 75-MeV/c π + beam from the TRIUMF M13 channel [10] was degraded by two thin plastic scintillators B1 and B2 and stopped in an 8-mm thick scintillator target (B3) at a rate of 5 × 10 4 π + /s. Pion tracking was provided by wire chambers (WC1 and WC2) at the exit of the beam line and two (x,y) sets of single-sided 0.3-mm thick planes of silicon strip detectors, S1 and S2, located immediately upstream of B3.