High-quality and excellent green-light-emitting poly(acenaphthylene) film: electrosynthesis and characterization

Hao, Qingli; Lei, Wu; Xie, Xingen; Xia, Mingzhu; Wang, Tianyi; Yang, Xin

doi:10.1039/c1py00008j

Cited by 9 publications

(7 citation statements)

References 37 publications

(44 reference statements)

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“…46 Given a molar mass dependence of PNIPAm it is worth considering the same for PAA. Here, it was necessary that the fluorescence measurements were performed in very dilute solution in order to limit the effect of self-quenching, 4,47,48 but the DOSY-NMR experiments were performed at concentrations of typically two orders of magnitude greater. The concentrations used for the DOSY-NMR diffusion measurements are listed in Table S4 of the ESI.…”

Section: Discussionmentioning

confidence: 99%

The pH-responsive behaviour of poly(acrylic acid) in aqueous solution is dependent on molar mass

et al. 2016

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Fluorescence spectroscopy on a series of aqueous solutions of poly(acrylic acid) containing a luminescent label showed that polymers with molar mass, Mn < 16.5 kDa did not exhibit a pH responsive conformational change, which is typical of higher molar mass poly(acrylic acid). Below this molar mass, polymers remained in an extended conformation, regardless of pH. Above this molar mass, a pH-dependent conformational change was observed. Diffusion-ordered nuclear magnetic resonance spectroscopy confirmed that low molar mass polymers did not undergo a conformational transition, although large molar mass polymers did exhibit pH-dependent diffusion.

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Section: Discussionmentioning

confidence: 99%

The pH-responsive behaviour of poly(acrylic acid) in aqueous solution is dependent on molar mass

et al. 2016

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“…It can be described as an appreciable rigid polymer exhibiting a non-draining character. OAN exhibits good stiffness as indicated by examination of molecular models. − …”

Section: Introductionmentioning

confidence: 98%

Surface Thermal Behavior and RT CO Gas Sensing Application of an Oligoacenaphthylene with p-Hydroxyphenylacetic Acid Composite

et al. 2022

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The current work describes room-temperature gas sensing performances using an oligoacenaphthylene (OAN)/p-hydroxyphenylacetic acid (p-HPA) composite. Based on inverse gas chromatography (IGC), the London dispersive surface energy γ s d is calculated by using 14 representative models. Even when the γ s d values of both OAN and the OAN/p-HPA composite are decreased as the temperature increases, the surface of OAN shows a higher value than that of the composite. The Gibbs surface free energy values of both are decreased with an increasing temperature. In our results, higher Lewis basic characters are observed in OAN and the OAN/p-HPA composite and the OAN/p-HPA surface exhibits a higher basicity compared to OAN. Because of the presence of phenolic groups in the OAN/p-HPA composite, the more important basic character drives a significant CO gas sensing ability with a sensitivity of 8.96% and good cycling stability as compared to the pristine counterparts. It is expected that the current study sheds light on a new pathway to exploring polymer composite materials for futuristic diverse and multiple applications, including IGC and gas sensor applications.

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“…On the other hand, poly(acenaphthylene) (PAcN), the subject of numerous studies (1)(2)(3)(4)(5)(6)(7), is characterized by the simplicity of its monomeric unit, the symmetry of its main chain, a bulky structure, and the presence of aromatic rings with p electron delocalization. These characteristics give this polymer interesting photochemical, photophysical, and electrical properties (8)(9)(10)(11)(12)(13)(14)(15)) that can be improved by copolymerization (16)(17)(18)(19)(20) or by introducing different substituents (21-23) into its structure.…”

Section: Introductionmentioning

confidence: 99%

Studying the Thermal Degradation of Different Polyacenaphthylenes via Thermogravimetric Analysis Combined With Fourier Transform Infrared Spectroscopy (TGA-FTIR)

Navarro

Bilbao

Laza

et al. 2014

Journal of Macromolecular Science, Part A

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In this study, the thermal behavior of polyacenaphthylene (PAcN) and partially modified polyacenaphthylene with Cl, Br, and H 2 PO 3 groups, both under air and nitrogen atmosphere, have been investigated. The influence of the molecular weight, the heating rate, and the introduced substituent have been studied. Thermogravimetric Analysis combined with Fourier Transform Infrared Spectroscopy was used to determine the thermal stabilities and the degradation mechanism. All polyacenaphthylene samples degrade through a depolymerisation process under a nitrogen atmosphere, whereas in air, elimination and thermo-oxidation reactions take place.

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High-quality and excellent green-light-emitting poly(acenaphthylene) film: electrosynthesis and characterization

Cited by 9 publications

References 37 publications

The pH-responsive behaviour of poly(acrylic acid) in aqueous solution is dependent on molar mass

The pH-responsive behaviour of poly(acrylic acid) in aqueous solution is dependent on molar mass

Surface Thermal Behavior and RT CO Gas Sensing Application of an Oligoacenaphthylene with p-Hydroxyphenylacetic Acid Composite

Studying the Thermal Degradation of Different Polyacenaphthylenes via Thermogravimetric Analysis Combined With Fourier Transform Infrared Spectroscopy (TGA-FTIR)

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