Single crystal Gaxlnl-xAs films have grown up on GaAs(100) substrate at 37512 and on InP(100) substrate at 39012, respectively, by the method of d-sputtering with using undoped GaInAs polycrystal as target. However, on Si(100) or Si( 111 ) substrates at 260 --39012, even at 46512, only polycrystalline films were obtained. In addition, the structure, composition, electrical characteristic and optical properties of the GaxIn 1 -xAs films were investigated using X-ray diffraction (XRD), reflection of high energy electron diffraction (RHEED), energy dispersion analyzer of X-ray (EDAX), Hall measurements and spectroscopic ellipsometry.