1997
DOI: 10.12693/aphyspola.92.958
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High Resistivity GaN Single Crystalline Substrates

Abstract: High resistivity 104 -106 Ω cm (300 K) GaN single crystals were obtained by solution growth under high Ν2 pressure from melted Ga with 0.1-0.5at.% of Mg. Properties of these crystals are compared with properties of conductive crystals grown by a similar method from pure Ga melt. In • particular, it is shown that Mg-doped GaN crystals have better structural quality in terms of FWHM of X-ray rocking curve and low angle boundaries. Temperature dependence of electrical resistivity suggests hopping mechanism of con… Show more

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Cited by 35 publications
(15 citation statements)
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“…The defects were also studied using Electron Energy Loss Spectroscopy (EELS) to determine their composition, as well as positron annihilation to determine the presence of vacancies and their conglomerations. Two types of samples have been studied: bulk samples grown by the high nitrogen pressure method from a solution of liquid gallium containing 0.1-0.5 at % Mg [15] and samples grown by MOCVD described earlier [16] using Cp 2 Mg at 1030°C.…”
Section: Methods Used In These Studiesmentioning
confidence: 99%
“…The defects were also studied using Electron Energy Loss Spectroscopy (EELS) to determine their composition, as well as positron annihilation to determine the presence of vacancies and their conglomerations. Two types of samples have been studied: bulk samples grown by the high nitrogen pressure method from a solution of liquid gallium containing 0.1-0.5 at % Mg [15] and samples grown by MOCVD described earlier [16] using Cp 2 Mg at 1030°C.…”
Section: Methods Used In These Studiesmentioning
confidence: 99%
“…The crystals are highly n-type which is most probably due to the incorporation of oxygen impurity into the crystal lattice. The addition of about 0.1 at% of magnesium into the growth solution leads to the change in the physical properties of the grown material [2]. As it was shown recently [3], with increasing Mg concentration, the crystals become highly resistive with hopping type conductivity at low temperatures changing eventually to the p-type with an activation energy of about 150 meV, at higher temperatures.…”
Section: Introductionmentioning
confidence: 92%
“…Bulk crystals were grown by the high nitrogen pressure method [8] from a solution of liquid gallium containing 0.1-0.5 at% Mg [9]. Similar procedure was applied to GaN : Be crystals.…”
mentioning
confidence: 99%