2000
DOI: 10.1006/jmsp.1999.8041
|View full text |Cite
|
Sign up to set email alerts
|

High-Resolution Laser Spectroscopy of YbCl: The A2Π–X2Σ+ Transition

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
1
1
1

Citation Types

2
20
3

Year Published

2000
2000
2017
2017

Publication Types

Select...
3
3

Relationship

1
5

Authors

Journals

citations
Cited by 19 publications
(25 citation statements)
references
References 22 publications
2
20
3
Order By: Relevance
“…Finally the observed vibrational spacing of the X state further confirmed the assignment of this state to the f 10 s 2 configuration. The x e of $337 cm À1 for the ground state is significantly higher than the 290 cm À1 found for the 4f 14 6s configuration of YbCl [8], however is consistent with expectations for 4f 10 6s 2 . Thus, vibrational frequencies in the q Supplementary data for this article are available on ScienceDirect (www.sciencedirect.com) and as part of the Ohio State University Molecular Spectroscopy Archives (http://msa.lib.ohio-state.edu/ jmsa_hp.htm).…”
Section: Introductionsupporting
confidence: 84%
See 3 more Smart Citations
“…Finally the observed vibrational spacing of the X state further confirmed the assignment of this state to the f 10 s 2 configuration. The x e of $337 cm À1 for the ground state is significantly higher than the 290 cm À1 found for the 4f 14 6s configuration of YbCl [8], however is consistent with expectations for 4f 10 6s 2 . Thus, vibrational frequencies in the q Supplementary data for this article are available on ScienceDirect (www.sciencedirect.com) and as part of the Ohio State University Molecular Spectroscopy Archives (http://msa.lib.ohio-state.edu/ jmsa_hp.htm).…”
Section: Introductionsupporting
confidence: 84%
“…It thus seems feasible that this state is therefore the X ¼ 8 state of the f 11 s configuration. If this is the case, the vibrational frequency should be $290 cm À1 as observed for the ground f 14 s configuration of YbCl [8]. Unfortunately, no fluorescence to other vibrational levels was observed from the C state and, if this configurational assignment is correct, then the 350 cm À1 spacing between the two weak transitions observed in dispersed fluorescence from the A state cannot be a vibrational spacing unless there is a very severe perturbation shifting the levels.…”
Section: DXmentioning
confidence: 80%
See 2 more Smart Citations
“…The spin-rotation splitting in the ground state has been discussed in detail in the previous study of the A 2 -X 2 + transition (1). As N increased, this splitting was also resolved in the present B-X spectra and the spin-rotation doubling of the rotational lines in the "blended" branches was used to definitively assign the two heads to the correct spin-rotation component, F 1 and F 2 , in the upper state.…”
Section: Resultsmentioning
confidence: 87%