1999
DOI: 10.1149/1.1391652
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High Sensitivity Flow Injection Analysis of Urea Using Composite Electropolymerized Polypyrrole‐Polyion Complex Film

Abstract: A highly sensitive and rapid flow injection system for urea analysis was constructed with a composite film of electropolymerized inactive polypyrrole (PPy) and a polyion complex incorporating urease. This system shows a sensitivity of 120 mV decade−1 and a lifetime of more than 80 assays. The origin of the high sensitivity of this system is attributed to an additional potential response of inactive PPy to ammonia or ammonium ion superimposed on the response to pH change. By injecting a concentrated buffer so… Show more

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Cited by 26 publications
(3 citation statements)
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“…The biosensors based on conducting polymers were discovered to treat penicillin and detect innumerable chromosomal disorders. A highly sensitive and rapid flow injection system for urea analysis was fabricated using the composite film of polypyrrole and a polyion complex [ 97 ]. Glucose biosensors are used to estimate glucose by the arrest of glucose oxidase enzymes with conducting polymers.…”
Section: Properties and Multifunctional Applications Of Conducting Polymersmentioning
confidence: 99%
See 1 more Smart Citation
“…The biosensors based on conducting polymers were discovered to treat penicillin and detect innumerable chromosomal disorders. A highly sensitive and rapid flow injection system for urea analysis was fabricated using the composite film of polypyrrole and a polyion complex [ 97 ]. Glucose biosensors are used to estimate glucose by the arrest of glucose oxidase enzymes with conducting polymers.…”
Section: Properties and Multifunctional Applications Of Conducting Polymersmentioning
confidence: 99%
“…The product derived through the blending of such fillers with CPs is defined as PNCs. The electrochemical supercapacitance of such PNCs is well documented [ 50 , 51 , 52 , 53 , 54 , 55 , 56 , 57 , 58 , 59 , 60 , 61 , 62 , 63 , 64 , 65 , 66 , 67 , 68 , 69 , 70 , 71 , 72 , 73 , 74 , 75 , 76 , 77 , 78 ], whereas limited research has been made on the implication of rare earth oxides (REOs) as fillers for semiconducting and electrochemical applications, as demonstrated in Table 1 [ 79 , 80 , 81 , 82 , 83 , 84 , 85 , 86 , 87 , 88 , 89 , 90 , 91 , 92 , 93 , 94 , 95 , 96 , 97 , 98 , 99 , 100 , 101 …”
Section: Introductionmentioning
confidence: 99%
“…1 This response has been exploited in many ammonia sensors. [2][3][4] Such ammonia sensors have also been used in combination with biological catalysts, that produce ammonia as a product of their reaction, to sense the substrate for these enzymes. An example is the case of urease to amperometrically sense urea.…”
Section: Introductionmentioning
confidence: 99%