The transitional nuclei 134 Ba and 133 Ba are investigated after multinucleon transfer employing the highresolution Advanced GAmma Tracking Array coupled to the magnetic spectrometer PRISMA at the Laboratori Nazionali di Legnaro, Italy, and after fusion-evaporation reaction at the FN tandem accelerator of the University of Cologne, Germany. The J π = 19/2 + state at 1942 keV in 133 Ba is identified as an isomer with a half-life of 66.6(20) ns corresponding to a B(E 1) value of 7.7(4) × 10 −6 e 2 fm 2 for the J π = 19/2 + to J π = 19/2 − transition. The level scheme of 134 Ba above the J π = 10 + isomer is extended to approximately 6 MeV. A pronounced backbending is observed athω = 0.38 MeV along the positive-parity yrast band. The results are compared to the high-spin systematics of the Z = 56 isotopes. Large-scale shell-model calculations employing the GCN50:82, SN100PN, SNV, PQM130, Realistic SM, and EPQQM interactions reproduce the experimental findings and elucidate the structure of the high-spin states. The shell-model calculations employing the GCN50:82 and PQM130 interactions reproduce alignment properties and provide detailed insight into the microscopic origin of this phenomenon in transitional 134 Ba.