The
wicking phenomenon, including wicking and hemiwicking, has
attracted increasing attention for its critical importance to a wide
range of engineering applications, such as thermal management, water
harvesting, fuel cells, microfluidics, and biosciences. There exists
a more urgent demand for anisotropic wicking behaviors since an increasing
number of advanced applications are significantly complex. For example,
special-shaped vapor chambers and heating atomizers in some electronic
cigarettes need liquid replenishing with various velocities in different
directions. Here, we report two-dimensional anisotropic hemiwicking
behaviors with elliptical shapes on laser structured prismatic microgrooves.
The prismatic microgrooves were fabricated via one-step femtosecond
laser direct writing, and the anisotropic hemiwicking behaviors were
observed when utilizing glycerol, glycol, and water as the test liquid.
Specifically, the ratios of horizontal wicking distance in directions
along short and long axes were tan 0°, tan 15°, tan 30°,
and tan 45° for samples with cross-angles of 0°, 30°,
60°, and 90°, respectively. The vertical water wicking front
displayed corresponding angles under the guidance of laser structured
prismatic microgrooves. Theoretical analysis shows that the wicking
distance is mainly dependent on the cross-angle θ and surface
roughness, in which the wicking distance is proportional to cos(θ/2).
Driven by the capillary pressure forming in the narrow microgrooves,
the liquid initially filled the valleys of microgrooves and then surrounded
and covered the prismatic ridges with laser-induced nanoparticles.
The abundant nanoparticles increased the surface roughness, leading
to the enhancement of wicking performance, which was further evidenced
by the larger wicking speed of the sample with more nanoparticles.
The mechanism of anisotropic hemiwicking behaviors revealed in this
work paves the way for wicking control, and the proposed prismatic
microgrooved surfaces with two-dimensional anisotropic hemiwicking
performance and superhydrophilicity could serve in a broad range of
applications, especially for the advanced thermal management with
specific heat load configurations.