The surface diffusion method was used to produce tungsten (W) nanopyramids coated with monolayer films of platinum (Pt) and gold (Au). Although the general structures of the nanopyramids were the same, the top of the nanopyramids was different from the Pt and Au cases, i.e., a monomer was observed for Pt, whereas a trimer observed for Au. The effects of simultaneous heating and the electric field on the structural evolution of nanopyramids were also studied. We observed that the broken nanopyramids were rapidly regenerated by heating in an electric field. The opening angles of field-emitted electrons were found to be approximately ±2° and ±2.5° for Pt and Au, respectively. From the obtained results, it was observed that the field-emission properties of all specimens were almost the same.