Gallium nitride (Gan) was epitaxially grown on nitrogen doped single layer graphene (n-SLG) substrates using chemical vapour deposition (cVD) technique. the results obtained using x-ray diffractometer (XRD) revealed the hexagonal crystal structure of GaN. Photoluminescence (PL) spectroscopy, energy dispersive x-ray (EDX) spectroscopy and x-ray photoelectron (XPS) spectroscopy revealed traces of oxygen, carbon and nitrogen occurring either as contamination or as an effect of doping during the GaN growth process. In addition, PL revealed a weak yellow luminescence peak in all the samples due to the presence of N-SLG. From the obtained results it was evident that, presence of n-SLG underneath Gan helped in improving the material properties. it was seen from the currentvoltage (i-V) response that the barrier height estimated is in good agreement with the Schottky-Mott model, while the ideality factor is close to unity, emphasizing that there are no surface and interface related inhomogeneity in the samples. the photodetector fabricated with this material exhibit high device performances in terms of carrier mobility, sensitivity, responsivity and detectivity. The hall measurement values clearly portray that, the GaN thus grown possess high electron contents which was beneficial in attaining extraordinary device performance. The fascinating properties of gallium nitride (GaN) such as wide direct band gap nature, ability to tune the band gap, high breakdown voltage, carrier mobility and chemical stability, make GaN a widely explored semiconductor material. The ability to operate at high power, high frequency and tolerance towards harsh environments is also a reason for preferring GaN 1-8. Conventionally, GaN is epitaxially grown using metal organic chemical vapour deposition (MOCVD), molecular beam epitaxy (MBE), hydride vapour phase vapour epitaxy (HVPE) and chemical vapour deposition (CVD) techniques 9-12. It is worth to note that GaN is still being epitaxially grown on foreign substrates such as silicon (Si), sapphire (Al 2 O 3) and silicon carbide (SiC). Sapphire is conventionally preferred as the substrate material due to its hexagonal crystal structure, availability in high crystalline quality and large area. But, due to the thermal and lattice variations between sapphire substrates and GaN, the aforesaid material properties of GaN cannot be achieved effectively. Also, poor thermal conductivity of sapphire restricts the usage of GaN in high power and optoelectronic devices 13-23. To overcome these deficiencies, it is beneficial to utilize graphene as an intermediate layer for the growth of GaN. Graphene, a two-dimensional (2D) material with a planar honeycomb like configuration of sp 2 hybridized carbon atoms, has attracted enormous interest for use in various optical and electronic device applications due to its unique material properties such as high optical transparency, thermal and electrical conductivity and