Contemporary communications systems use large arrays in order to exploit
the spatial domain requiring multiple radio-frequency (RF) chains
leading to prohibitive cost and power consumption. Spatial degrees of
freedom are also achieved by utilizing the polarization states of an
electromagnetic wave. To this end, we propose a polarization-state
modulation system based on carrier-wave reflections from a
reconfigurable intelligent surface (RIS), where a sequence of data bits
is mapped to polarization states. We consider a system with an upper
millimeter-wave or low-THz RF source so that the channel model is
line-of-sight-dominant. The data symbol constellation consists of
sixteen quaternion-valued symbols, of which two correspond to linear
polarizations and the remaining twelve represent elliptical
polarizations. Our channel models consist of both additive white
Gaussian noise and impulse noise. We utilize the Weiszfeld algorithm and
generalized M-estimators (GM-estimators) to handle the impulse noise and
robustly decode the PSM signals. Furthermore, we train and evaluate
quaternion neural networks (QNN) for decoding PSM signals using seven
different activation methods. Our numerical experiments indicate that
the RIS is capable of directing signal power toward the location of the
receiver. The bit error rate performance of our QNNs and robust decoders
exceeds that of OFDM-BPSK.