“…2D materials, consisting of a single or several atomic layers such as graphene, [ 12 ] transition metal dichalcogenides (TMDs), [ 13–16 ] or GaSe, [ 17–21 ] represent an emergent class of materials with extraordinary electronic and physicochemical properties, and are a highly attractive prospect for chemiresistor gas sensors. [ 12,17,22–28 ] The gas‐sensing properties of graphene, [ 29–31 ] MoS 2 , [ 25,32 ] MoSe 2 , [ 33 ] MoTe 2 , [ 34,35 ] WS 2 , [ 36 ] SnS 2 , [ 37,38 ] PtS 2 , [ 39 ] PtSe 2 , [ 40 ] black phosphorus, [ 41 ] as well as graphene/MoS 2 heterostructures [ 42,43 ] have been the subjects of recent investigations. GaSe, a layered metal–monochalcogenide III–VI semiconductor, shows excellent electrical and optical properties, [ 13,17,44 ] such as a high on/off ratio, [ 45,46 ] high Hall mobility, [ 45,47 ] upconversion luminescence, [ 48 ] high photoresponsivity, a giant and linear piezophototronic response, [ 49,50 ] and strong second‐harmonic generation, [ 51 ] thus making it a great candidate material for applications in nonlinear optics, terahertz devices, sensors, and spintronics.…”