2010
DOI: 10.1002/elan.201000087
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History of Electroanalytical Methods

Abstract: There are many historical reviews on electrochemistry as well as on analytical chemistry, where-as hardly any survey of the history of electroanalytical methods exists. This contribution is an approach to provide a short overview on the development of the electroanalytical methods, electrodes and electrochemical sensors. Electrogravimetry belongs to the oldest quantitative procedures introduced 1864 by Wolcott Gibbs. Roots are even older and are represented by "voltameters". Closely related to electrogravimetr… Show more

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Cited by 53 publications
(41 citation statements)
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“…Lubert and Kalcher recently provided a history of electroanalytical methods in which the reader could find a wider view of the field. 21 First electroanalytical determination of copper in copper-nickel coins was accomplished by electrogravimetric method on platinum electrodes in the nineteenth century. Later, polagraphy, rewarded by a Nobel Prize for J. Heyrovsky, was developed with dropping mercury electrode and important developments have been then conducted on both analytical methods and materials.…”
Section: Bulk "Conventional" Electrode Materialsmentioning
confidence: 99%
“…Lubert and Kalcher recently provided a history of electroanalytical methods in which the reader could find a wider view of the field. 21 First electroanalytical determination of copper in copper-nickel coins was accomplished by electrogravimetric method on platinum electrodes in the nineteenth century. Later, polagraphy, rewarded by a Nobel Prize for J. Heyrovsky, was developed with dropping mercury electrode and important developments have been then conducted on both analytical methods and materials.…”
Section: Bulk "Conventional" Electrode Materialsmentioning
confidence: 99%
“…In this type of solidcontact ISE, the conducting polymer is coated with a conventional ion-selective membrane, and the ion-selectivity is determined mainly by the ion-selective membrane. For example, potentiometric sensors based on a glassy carbon electrode covered with polyaniline and various thiacalix [4]arene ionophores have been developed and applied for the successful determination of Ag + ions [29]. Other configurations for solid-contact ISEs recently reported involve the use of carbon cloth coated with a conventional plasticized PVC-based K(+)-selective membrane [30], carbon nanotubes (CNTs) drop-coated with a K + -selective polyacrylic membrane [31], PVC-based molecularly imprinted polymers [32] and graphene coated with an ionophore-doped polymeric membrane [33].…”
Section: Potentiometric Sensorsmentioning
confidence: 99%
“…The former wanted to introduce the device as "Haber electrode" causing protests of Cremer. The latter should be given full appreciation of the invention of the glass electrode though Haber dominates the literature [4]. Today, the electrochemical sensor plays an essential analytical role in the fields of environmental conservation and monitoring, disaster and disease prevention, and industrial analysis.…”
Section: Introductionmentioning
confidence: 99%
“…Since Jaroslav Heyrovský introduced polarography as analytical method in 1922, the development of voltammetry is generally related with increase in sensitivity [1][2][3]. In amperometry and voltammetry sensitivity is defined by the signal-to-noise ratio.…”
Section: Introductionmentioning
confidence: 99%