2019
DOI: 10.1039/c9ra03780b
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Hollow Cu-doped NiO microspheres as anode materials with enhanced lithium storage performance

Abstract: Doping is an effective way to optimize the properties of electrode material. Here hollow Cu-doped NiO microspheres were obtained via hydrothermal way, which exerts prominent initial capacity and better rate capability as anode materials.

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Cited by 48 publications
(21 citation statements)
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“…[50], and 864.07[50] which clearly corresponds to NiO. This analysis confirms the presence of in-situ NiO dopant in the FPCB-derived CuO nanoflakes[51]. The ICP and XRF analysis are carried out which indicates the major elements of the nanoflakes is Cu with a 3-4% of Ni.The microstructure, crystal structure, and elemental mapping of the NiO-doped CuO nanoflakes were investigated using HR-TEM imaging, SAED, and TEM-EDS analysis represented in Figure4.…”
supporting
confidence: 61%
See 1 more Smart Citation
“…[50], and 864.07[50] which clearly corresponds to NiO. This analysis confirms the presence of in-situ NiO dopant in the FPCB-derived CuO nanoflakes[51]. The ICP and XRF analysis are carried out which indicates the major elements of the nanoflakes is Cu with a 3-4% of Ni.The microstructure, crystal structure, and elemental mapping of the NiO-doped CuO nanoflakes were investigated using HR-TEM imaging, SAED, and TEM-EDS analysis represented in Figure4.…”
supporting
confidence: 61%
“…The bandgap energy for CuO was measured as 1.6 eV, which is higher than the value for bulk CuO (1.2 eV) [57] and lower than NiO nanoparticles (3.8 eV) [51]. The shift of the energy from one level to another can be attributed to quantum confinement in the nanocrystal structure.…”
Section: Nanoscale Advances Accepted Manuscriptmentioning
confidence: 76%
“…In addition, when the Ni is substituted into CuO, the Ni ions occupy the lattice position of the Cu ions. Because the radii of the Ni 2+ (0.55 Å) and Cu 2+ (0.57 Å) ions are similar, the introduction of Ni will not cause a strong distortion of the CuO structure. With the increasing doping concentration, the film doped with 20% Ni shows the strongest peak intensity.…”
Section: Results and Discussionmentioning
confidence: 98%
“…(scan rate of 10 mV s −1 ) [ 128 ]. The authors in work [ 129 ] synthesized ultrafine SnO 2 nanorods-rGO nanocomposite while using a two-step hydrothermal method (using KMnO 4 ) and those electrode materials in supercapacitors achieved the specific capacitance of 262.2 F g −1 (at 100 mA g −1 ). Coulombic efficiency is equal to 96.1% after 6000 cycles, which indicates high electrochemical performance of the system.…”
Section: Resultsmentioning
confidence: 99%