For a complex Lie group G with a real form G 0 ⊂ G, we prove that any Hamiltionian automorphism φ of a coadjoint orbit O 0 of G 0 whose connected components are simply connected, may be approximated by holomorphic O 0 -invariant symplectic automorphism of the corresponding coadjoint orbit of G in the sense of Carleman, provided that O is closed. In the course of the proof, we establish the Hamiltonian density property for closed coadjoint orbits of all complex Lie groups.