Cadmium-based quantum
dots (Cd-QDs) show decent performance for
lighting applications due to good color saturation, an excellent high
quantum yield, and a narrow full-width at half-maximum. However, the
intrinsic toxicity of Cd is a major hindrance to related applications,
especially in the biological field. ZnSe, with a band gap of 2.7 eV
and lower toxicity than CdSe or CdS, is promising as a blue luminescent
material. Herein, we mainly reported the preparation and luminescence
properties of nanostructured ZnSe/ZnS multilayer thin films with bright
blue photoluminescence. The photoluminescence spectrum contained two
emission peaks, located at about 442 nm (near band-edge emission)
and 550 nm (defect-related emission), respectively. More importantly,
the photoluminescence performance and decay were explored in detail
through low-temperature photoluminescence spectra. In addition, the
nanostructured ZnSe/ZnS multilayer thin films showed favorable photostability.