How to force a classical chelating ligand to a metal non-chelating bridge: the observation of a rare coordination mode of diethanolamine in the 1D complex {[Cu2(Piv)4(H3tBuDea)](Piv)}n

Nesterova, Oksana V.; Kirillova, Marina V.; Silva, M. Fátima C. Guedes da; Boča, Roman; Pombeiro, Armando J. L.

doi:10.1039/c3ce41657g

Cited by 11 publications

(2 citation statements)

References 56 publications

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“…Later, Fujiwara [309][310][311] and Pombeiro [312][313][314][315] demonstrated that this reaction can be sufficiently improved if various catalysts are used. Derivatives of copper, vanadium, and other metals served as catalysts.…”

Section: Discussionmentioning

confidence: 99%

New Trends in Oxidative Functionalization of Carbon–Hydrogen Bonds: A Review

Shul’pin

2016

Catalysts

174

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This review describes new reactions catalyzed by recently discovered types of metal complexes and catalytic systems (catalyst + co-catalyst). Works of recent years (mainly 2010-2016) devoted to the oxygenations of saturated, aromatic hydrocarbons and other carbon-hydrogen compounds are surveyed. Both soluble metal complexes and solid metal compounds catalyze such transformations. Molecular oxygen, hydrogen peroxide, alkyl peroxides, and peroxy acids were used in these reactions as oxidants.

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Section: Discussionmentioning

confidence: 99%

New Trends in Oxidative Functionalization of Carbon–Hydrogen Bonds: A Review

Shul’pin

2016

Catalysts

174

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“…Acetate can form a paddle-wheel Cu(II) dimer unit [Cu 2 (CH 3 COO) 4 ], which is a good building block for molecule-based magnets and multidimensional coordination polymers [12][13][14][15]. In dimeric units, strong magnetic interactions are operative within the Cu 2 species, and the units form interesting coordination networks because of the vacant sites at the apical positions.…”

Section: Introductionmentioning

confidence: 99%

Anion-Dependent Cu(II) Coordination Polymers: Geometric, Magnetic and Luminescent Properties

et al. 2022

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A one-dimensional (1D) coordination polymer [Cu2(bpba)(CH3COO)4] (1) and a two-dimensional (2D) coordination polymer [Cu(bpba)2(H2O)(NO3)](NO3)∙2H2O∙MeOH (2) were synthesized by the reaction between Cu(CH3COO)2∙H2O/Cu(NO3)2∙3H2O and bis(4-pyridyl)benzylamine (bpba). The Cu(II) ions of 1 and 2 have distorted-square pyramidal coordination with a paddle-wheel structure and an octahedral geometry, respectively. By coordinating the Cu(II) ions and bpba ligands, 1 and 2 formed zigzag 1D and puckered 2D coordination polymers, respectively. Polymer 1 exhibits strong emissions at 355 and 466 nm, whereas polymer 2 exhibits strong emissions only at 464 nm. The emissions are strongly dependent on the geometry of the Cu(II) ions linked by the bpba and anionic ligands. Polymer 1 exhibits a very strong antiferromagnetic interaction within the paddle-wheel dimer, whereas polymer 2 exhibits a very weak antiferromagnetic interaction through the bpba linkers and/or space.

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Alkane Carbonylation and Carbene Insertion Reactions

Phillips

Pombeiro

2018

Alkane Functionalization

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How to force a classical chelating ligand to a metal non-chelating bridge: the observation of a rare coordination mode of diethanolamine in the 1D complex {[Cu₂(Piv)₄(H₃tBuDea)](Piv)}_n

Cited by 11 publications

References 56 publications

New Trends in Oxidative Functionalization of Carbon–Hydrogen Bonds: A Review

New Trends in Oxidative Functionalization of Carbon–Hydrogen Bonds: A Review

Anion-Dependent Cu(II) Coordination Polymers: Geometric, Magnetic and Luminescent Properties

Alkane Carbonylation and Carbene Insertion Reactions

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