Air pollution over Lake Baikal originating
from anthropogenic emissions
as well as wildfire events and secondary organic aerosol (SOA) formation
poses a threat to this world heritage ecosystem. During a ship expedition
in 2018, ambient aerosol particles were sampled on filters at different
locations of Lake Baikal and extracted to obtain the fraction of water-soluble
organic aerosol (WSOA). Subsequent analysis by Fourier transform ion
cyclotron resonance (FTICR) mass spectrometry with direct-infusion
electrospray ionization (ESI) in both ionization modes provides insights
into the molecular composition of polar and high-molecular-weight
species in WSOA. Light absorption spectral dependence determined by
absorption Ångstrom exponent (AAE) is correlated to summed compound
class abundancies to identify light-absorbing compounds. Most detected
species are heavily oxidized, associated with intense atmospheric
aging, and contain significant amounts of nitrogen or sulfur, with
the most abundant compound classes being CHO, CHON, and CHOS. Nitrogen-containing
species are more frequently found in positive ESI and correlate well
with AAE. Oxygen-to-nitrogen ratios (O/N) larger than 3 indicate organic
nitrates, and also less oxidized nitrogen species can be linked to
brown carbon (BrC). ESI in both ionization modes provides complementary
molecular information with, on the one hand, more sensitive detection
of high average carbon oxidation state (OSC) and low-volatility
oxidized organic aerosol species in negative mode, and on the other
hand, lower OSC (OSC < 0) species as well
as oligomers and potential biomass burning organic aerosol in positive
mode. Additionally, a great overlap of sum formulae was found at all
sampling sites along the expedition route, regardless of the potential
primary emission sources, indicating strong atmospheric aging and
mixing, leading to a similar oxidized organic aerosol (OOA) from different
primary sources.