2021
DOI: 10.3390/polym13152546
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Hybrid Copolymerization of Ethylene Oxide and tert-Butyl Methacrylate with Organocatalyst

Abstract: Hybrid copolymerization of structurally different, reactivity and mechanism distinct monomers (e.g., cyclic and vinyl type monomers) is of great interest and challenge for both academic research and practical application. Herein, ethylene oxide-co-tert-butyl methacrylate-co-poly(ethylene glycol) benzyl methacrylate (EO-co-BMA-co-bPEO), a statistical copolymer was synthesized via hybrid copolymerization of EO and BMA using an uncharged, non-nucleophilic organobase t-BuP4 as the catalyst. Detailed characterizati… Show more

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Cited by 4 publications
(2 citation statements)
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“…[ 19–21 ] Anyhow, hybrid copolymerization is becoming a powerful and convenient strategy to synthesize polymers with tailored structures. [ 22–25 ]…”
Section: Introductionmentioning
confidence: 99%
See 1 more Smart Citation
“…[ 19–21 ] Anyhow, hybrid copolymerization is becoming a powerful and convenient strategy to synthesize polymers with tailored structures. [ 22–25 ]…”
Section: Introductionmentioning
confidence: 99%
“…[19][20][21] Anyhow, hybrid copolymerization is becoming a powerful and convenient strategy to synthesize polymers with tailored structures. [22][23][24][25] Transesterification often happens in organic reactions. It is inevitable for the polymerization systems with monomers having esters groups, which may make the polymerization mechanism and polymer structures more complex.…”
Section: Introductionmentioning
confidence: 99%