Hybrid HMX multi-level assembled under the constraint of 2D materials with efficiently reduced sensitivity and optimized thermal stability

Song, Xiaomin; Huang, Longjin; Peng, Rufang; Huang, Qi; Xu, Jinjiang; Sun, Jie

doi:10.1016/j.dt.2024.03.007

Cited by 2 publications

(1 citation statement)

References 60 publications

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“…HMX has gained widespread use in various military and civil applications due to its exceptional comprehensive properties [9] , [10] , [11] . However, its application is somewhat constrained by its relatively high shock sensitivity [12] , [13] , [14] , [15] , [16] . Modifying HMX crystals through recrystallization proves effective in significantly enhancing explosive safety while striking a balance between energy, low sensitivity, and cost, thereby expanding its application range [17] .…”

Section: Introductionmentioning

confidence: 99%

Facilitating polymorphic crystallization of HMX through ultrasound and trace additive assistance

Li,

Huang

et al. 2024

Ultrasonics Sonochemistry

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Section: Introductionmentioning

confidence: 99%

Facilitating polymorphic crystallization of HMX through ultrasound and trace additive assistance

Li,

Huang

et al. 2024

Ultrasonics Sonochemistry

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Solvent Vapor/Gas-Induced Guest Transport and Exchange of a Nonporous Organic Crystal to Construct Smart Host–Guest Energetic Materials

Song,

Zhang,

Jin

et al. 2024

ACS Appl. Mater. Interfaces

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Supramolecular materials with advanced properties constructed by intermolecular interactions have attracted extensive attention in many fields, such as sensing, catalysis, and biomedicine. However, in the field of energetic materials, limited by the tight-packed crystal structure of explosives and the strong intermolecular interaction forces, most supramolecular explosives can only be obtained in organic solution or under extreme external loading (high temperature/ high pressure). Given the practical issues such as safety risks, operational difficulties, serious environmental pollution, and large-scale production of the existing technology, a new method of constructing host−guest explosives by solvent vapor/gas induction is proposed. This gas−solid reaction method takes advantage of the metastable properties from the explosives solvate (HNIW/ACN), and cleverly opens a fast channel for gas molecules to enter the explosives cell cavities, which results in the highly efficient preparation of the host−guest explosives (HNIW/CO 2 and HNIW/N 2 O). The embedding of functional gas molecules greatly improves the structural stability and comprehensive performance of the explosive skeleton, and the detonation velocity of HNIW/N 2 O even reaches 9802 m•s −1 , which is higher than that of ε-HNIW (9455 m•s −1 ). In addition, compared with ε-HNIW, HNIW/CO 2 and HNIW/N 2 O exhibit high energy but low sensitivity, enhanced thermal stability, and combustion properties, which present a potential prospect in the field of energetic materials. The new method effectively overcomes the high-energy barrier of nonporous organic explosives, offering the advantages of simplicity, safety, efficiency, and environmental friendliness. This study provides a valuable pathway for constructing advanced supramolecular energetic materials, which contributes to the enrichment of supramolecular engineering systems.

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Hybrid HMX multi-level assembled under the constraint of 2D materials with efficiently reduced sensitivity and optimized thermal stability

Cited by 2 publications

References 60 publications

Facilitating polymorphic crystallization of HMX through ultrasound and trace additive assistance

Facilitating polymorphic crystallization of HMX through ultrasound and trace additive assistance

Solvent Vapor/Gas-Induced Guest Transport and Exchange of a Nonporous Organic Crystal to Construct Smart Host–Guest Energetic Materials

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