Hybrid shell of MXene and reduced graphene oxide assembled on PMMA bead core towards tunable thermoconductive and EMI shielding nanocomposites

Vu, Minh Canh; Mani, Dineshkumar; Kim, Jun‐Beom; Jeong, Tae‐Hyeong; Park, Seongmin; Murali, G.; In, Insik; Won, Jong-Chan; Lošić, Dušan; Lim, Choong‐Sun; Kim, Sung‐Ryong

doi:10.1016/j.compositesa.2021.106574

Cited by 74 publications

(18 citation statements)

References 50 publications

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“…The T HRI of the untreated and modified silk is 113°C and 113.75°C, respectively, while the T 50 (temperature at weight loss of 50 wt%) is 398.42 and 489.13°C, respectively. Additionally, the residual amount of the modified silk with 40.62% is greater than that of the untreated silk with 33.53% at 600°C, it can be contributed to the amount of undecomposed Fe 3 O 4 particles 74,75 . These results indicated the modification treatment did not weaken the thermal stability of silk fibers.…”

Section: Resultsmentioning

confidence: 83%

“…The temperature at maximum weight loss for the untreated and modified silk fabrics is 333.5°C and 328.7°C, respectively 72 . Further, the heat resistance index (HRI) for the untreated and modified silk fabric was calculated according to T 5 and T 30 (the temperature at weight loss of 5 wt% and 30 wt%, respectively) as followed by 73,74 :

T_{HRI} goodbreak= 0.49 goodbreak\times ([], T_{5} goodbreak+ 0.6 goodbreak\times ((), T_{30} goodbreak- T_{5}))

…”

Section: Resultsmentioning

confidence: 99%

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Enhancement of natural dyeing properties and UV resistance of silk fibers modified by phenylboronic acid/hydroxypropyl‐β‐cyclodextrin functionalized Fe₃O₄ particle

Meng

et al. 2022

J of Applied Polymer Sci

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Silk fabrics with improved UV protection and natural dyeability were prepared by in‐situ deposition method, using 4‐carboxylphenylboronic acid (4‐CPBA) functionalized 2‐hydroxypropyl‐β‐cyclodextrin (HP‐β‐CD) covered magnetic Fe3O4 particles. The as‐prepared silk fabrics were characterized by FT‐IR, XRD, XPS, TG‐DSC, and SEM techniques. The ultraviolet resistance and dyeing properties with grape seed proanthocyanidin extract (GSPE) for silk fabrics under different dyeing conditions was discussed in detail. The results showed that the phenylboronic acid functionalized HP‐β‐CD covered Fe3O4 particle was deposited on the surface of silk fiber, enhancing the adsorption and fixation of GSPE, even in weak alkaline dyebath. PBA/HP‐β‐CD/Fe3O4 modified silk fiber surface exhibited the higher color strength (K/S) and UV protection factor (UPF) than those of untreated silk fabrics under different dyeing conditions due to specific recognition and adsorption of cis‐diol‐containing GSPE dyes. Moreover, modified silk fabric possessed good color fastness after 20 times of washing circles. This study is expected to provide a promising approach to achieve functional protection and dyeing of silk fabrics.

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Section: Resultsmentioning

confidence: 83%

T_{HRI} goodbreak= 0.49 goodbreak\times ([], T_{5} goodbreak+ 0.6 goodbreak\times ((), T_{30} goodbreak- T_{5}))

…”

Section: Resultsmentioning

confidence: 99%

Enhancement of natural dyeing properties and UV resistance of silk fibers modified by phenylboronic acid/hydroxypropyl‐β‐cyclodextrin functionalized Fe₃O₄ particle

Meng

et al. 2022

J of Applied Polymer Sci

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“…In Figure a and b, the thermal conductivity and EMI SE of M- o -GWF/thermoplastic composites prepared using the same process are in the range of 7.40–9.26 W m –1 K –1 and 55.7–62.5 dB, respectively, at a filler content of 2.91–3.55 wt % (also see Figures S20 and S21 and Tables S9 and S10). Figure c and Table S11 indicate that our samples with different thermoplastic matrices can also achieve superior EMI SE and thermal conductivity performance simultaneously, compared to existing thermoplastic composites. ,,− In Figure d and e, a comparison test was done to present the practical effect of EMI protection of the device with M- o -GWF/PE composite plates. A light-emitting diode (LED) display panel coupled with a Bluetooth receiver was sealed in a shielding case with a cutout in an area of 5 mm × 10 mm.…”

Section: Results and Discussionmentioning

confidence: 98%

Enhanced Electromagnetic Shielding and Thermal Conductive Properties of Polyolefin Composites with a Ti₃C₂T_x MXene/Graphene Framework Connected by a Hydrogen-Bonded Interface

et al. 2022

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The rapid increase of operation speed, transmission efficiency, and power density of miniaturized devices leads to a rising demand for electromagnetic interference (EMI) shielding and thermal management materials in the semiconductor industry. Therefore, it is essential to improve both the EMI shielding and thermal conductive properties of commonly used polyolefin components (such as polyethylene (PE)) in electronic systems. Currently, melt compounding is the most common method to fabricate polyolefin composites, but the difficulty of filler dispersion and high resistance at the filler/filler or filler/matrix interface limits their properties. Here, a fold fabrication strategy was proposed to prepare PE composites by incorporation of a well-aligned, seamless graphene framework premodified with MXene nanosheets into the matrix. We demonstrate that the physical properties of the composites can be further improved at the same filler loading by nanoscale interface engineering: the formation of hydrogen bonds at the graphene/MXene interface and the development of a seamlessly interconnected graphene framework. The obtained PE composites exhibit an EMI shielding property of ∼61.0 dB and a thermal conductivity of 9.26 W m −1 K −1 at a low filler content (∼3 wt %, including ∼0.4 wt % MXene). Moreover, other thermoplastic composites with the same results can also be produced based on our method. Our study provides an idea toward rational design of the filler interface to prepare high-performance polymer composites for use in microelectronics and microsystems.

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“…Vu et al 173 prepared a hybrid shell of MXene and rGO assembled on a PMMA bead as a core (Fig. 14a).…”

Section: Fiber Core-shell Structuresmentioning

confidence: 99%

MXene in core–shell structures: research progress and future prospects

et al. 2022

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Hybrid shell of MXene and reduced graphene oxide assembled on PMMA bead core towards tunable thermoconductive and EMI shielding nanocomposites

Cited by 74 publications

References 50 publications

Enhancement of natural dyeing properties and UV resistance of silk fibers modified by phenylboronic acid/hydroxypropyl‐β‐cyclodextrin functionalized Fe₃O₄ particle

Enhancement of natural dyeing properties and UV resistance of silk fibers modified by phenylboronic acid/hydroxypropyl‐β‐cyclodextrin functionalized Fe₃O₄ particle

Enhanced Electromagnetic Shielding and Thermal Conductive Properties of Polyolefin Composites with a Ti₃C₂T_x MXene/Graphene Framework Connected by a Hydrogen-Bonded Interface

MXene in core–shell structures: research progress and future prospects

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Hybrid shell of MXene and reduced graphene oxide assembled on PMMA bead core towards tunable thermoconductive and EMI shielding nanocomposites

Cited by 74 publications

References 50 publications

Enhancement of natural dyeing properties and UV resistance of silk fibers modified by phenylboronic acid/hydroxypropyl‐β‐cyclodextrin functionalized Fe3O4 particle

Enhancement of natural dyeing properties and UV resistance of silk fibers modified by phenylboronic acid/hydroxypropyl‐β‐cyclodextrin functionalized Fe3O4 particle

Enhanced Electromagnetic Shielding and Thermal Conductive Properties of Polyolefin Composites with a Ti3C2Tx MXene/Graphene Framework Connected by a Hydrogen-Bonded Interface

MXene in core–shell structures: research progress and future prospects

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Product

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Enhancement of natural dyeing properties and UV resistance of silk fibers modified by phenylboronic acid/hydroxypropyl‐β‐cyclodextrin functionalized Fe₃O₄ particle

Enhancement of natural dyeing properties and UV resistance of silk fibers modified by phenylboronic acid/hydroxypropyl‐β‐cyclodextrin functionalized Fe₃O₄ particle

Enhanced Electromagnetic Shielding and Thermal Conductive Properties of Polyolefin Composites with a Ti₃C₂T_x MXene/Graphene Framework Connected by a Hydrogen-Bonded Interface