Optical soliton dynamics in a waveguide can cause the extreme alteration of the temporal and spectral shape of a propagating light pulse. They occur at watt to kilowatt peak power in glass-core optical fibres and up to the gigawatt level in gas-filled microstructured hollow-core fibres. Here we demonstrate, for the first time, optical soliton dynamics in conventional large-core hollow capillary fibres. Our analysis and modelling show that this enables further scaling of soliton effects by several orders of magnitude to the multi-mJ energy and terawatt peak power level. We experimentally demonstrate two key soliton effects. First, we observe self-compression to sub-cycle pulses and infer the creation of sub-femtosecond field waveforms-a route to high-power optical attosecond pulse generation. Second, we efficiently generate continuously tunable high-energy (1-13 µJ) pulses in the vacuum and deep ultraviolet spectral region (110 nm to 400 nm) through resonant dispersive-wave emission. This new regime of high-energy ultrafast soliton effects promises to be the foundation of a new generation of table-top light sources for ultrafast strong-field physics and advanced spectroscopy. * j.travers@hw.ac.uk; http://lupo-lab.com arXiv:1811.05877v1 [physics.optics]