Chemical Mechanical Polishing of Copper (Cu-CMP) is an important yet poorly-understood nanofabrication technique. In this work, we demonstrate that the degree of non-uniformity in polishing rates, described by the new quantity MRRNU, relates to the lubrication conditions of the polishing couple. MRRNU is the difference between the highest and lowest material removal rates (MRRs) recorded across the wafer surface, normalized by the average MRR. The polish rate non-uniformity that this quantity encapsulates is shown to transition from negative (wafer-scale dishing) to positive (wafer-scale doming) with increasing Sommerfeld number, for the pad and slurry chemistry used here. This is explained by the presence of co-existing lubrication zones in the pad-wafer interface. Each of the zones described, namely the edge zone, hydrodynamic zone and suppression zone, demonstrate a different relationship between pressure and removal rate, resulting in variation in MRR across the wafer. Chemical Mechanical Polishing, or CMP, is a nanofabrication technique used to simultaneously remove material from surfaces and planarize them. It is commonly used within the semiconductor industry to process surfaces of silicon oxide, silicon nitride and both polycrystalline and single-crystal silicon. It has also been used with metals such as aluminum, tungsten and copper, where it is used in conjunction with etching and electroplating techniques to form nanoscale features such as interconnects. A more complete description of the CMP process is available in the literature. 1 Successful application of CMP requires understanding how withinwafer-non-uniformity (WIWNU) develops during polishing. Several factors are known to influence WIWNU for copper CMP, including slurry chemistry, 2,3 pad wear 4 and pad topography. 5 For a given slurry chemistry and pad, WIWNU is also influenced by the polishing pressure and velocity. 6 However, a comprehensive examination of the effects of pressure and velocity on WIWNU has not been conducted. In this study, the combined influence of pressure and velocity on WI-WNU is summarized by the dimensionless Sommerfeld number (So), describing the lubrication regime and hence load transfer mechanism in CMP. The change in WIWNU during polishing, described by the new quantity MRRNU, is shown to correlate strongly with the Sommerfeld number. MRRNU is obtained by measuring the polishing material removal rate (MRR) across the radius of the wafer, then normalizing the difference between the maximum and minimum rates obtained by the mean MRR. Three zones of polishing contact which coexist during polishing are postulated to explain the observed correlation between So and MRRNU.During polishing, the pressure applied to the polishing couple can be transferred between the pad and the wafer through direct contact with the pad and abrasives, through the intervening fluid, or through a combination of both. The mode of load transfer is characterized in tribology by the construction of a Stribeck curve. This is a plot of the Sommerfeld ...