2014
DOI: 10.1039/c4ra04647a
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Hydrogen physisorption in ionic solid compounds with exposed metal cations at room temperature

Abstract: Phenol- and phloroglucinol-based ionic solid complexes for room temperature hydrogen storage via physisorption.

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Cited by 8 publications
(6 citation statements)
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“…In addition, the nano-pores in the range of 1.5-2 nm were also detected for the MTA-Li complex, which arise mainly from the inefficient packing of the molecules with a lack of topological selfcomplementarity. 48,49 The porous structure of MTF-Li was further investigated by scanning electron microscopy (SEM). The SEM image of MTF-Li (Fig.…”
Section: Synthesis and Characterizationmentioning
confidence: 99%
“…In addition, the nano-pores in the range of 1.5-2 nm were also detected for the MTA-Li complex, which arise mainly from the inefficient packing of the molecules with a lack of topological selfcomplementarity. 48,49 The porous structure of MTF-Li was further investigated by scanning electron microscopy (SEM). The SEM image of MTF-Li (Fig.…”
Section: Synthesis and Characterizationmentioning
confidence: 99%
“…Notably, the apparatus with an empty sample chamber was thoroughly calibrated prior to the test to rule out a linear increase of uptake upon gas compression. The instrument calibration and the experimental considerations are published elsewhere [11][12][13]15,18] .…”
Section: Resultsmentioning
confidence: 99%
“…Hydrogen adsorption measurements were performed by following the standard practice guidelines provided by the US Department of Energy to minimize potential errors in the hydrogen uptake measurement [30][31][32] . The instrument calibration and the experimental considerations are published elsewhere [11][12][13]15,18] .…”
Section: Characterizationsmentioning
confidence: 99%
“…[5][6][7] Many technical challenges such as efficient storage, safer refueling, and higher driving range are major barriers for market acceptability of H-FCV. 8,9 In this regard, compressed H 2 storage seems to be promising if high storage capacity for driving range of 300 miles can be achieved. [10][11][12] Currently, types III and IV H 2 storage tanks are commonly used by fuel cell vehicle manufacturer.…”
Section: Introductionmentioning
confidence: 99%
“…Commercial, automotive manufacturers such as Toyota, Honda, BMW, and Hyundai have come forward with their hydrogen fuel cell vehicles (H‐FCV) . Many technical challenges such as efficient storage, safer refueling, and higher driving range are major barriers for market acceptability of H‐FCV . In this regard, compressed H 2 storage seems to be promising if high storage capacity for driving range of 300 miles can be achieved …”
Section: Introductionmentioning
confidence: 99%