Hydrogen-rich syngas production from the lignocellulosic biomass by catalytic gasification: A state of art review on advance technologies, economic challenges, and future prospectus

Ghodke, Praveen Kumar; Sharma, Amit Kumar; Arun, Jayaseelan; Gopinath, Kannappan Panchamoorthy

doi:10.1016/j.fuel.2023.127800

Cited by 68 publications

(17 citation statements)

References 123 publications

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“…The catalytic mechanism of zirconium‐based catalysts in this process can be described as follows. [ 108 ] First, biomass activation: the catalysts activate the biomass by breaking down complex organic molecules into simpler compounds, including CO, CO 2 , H 2 , and CH 4 . Second, gasification reaction: the activated biomass is introduced into a gasifier along with steam and/or air.…”

Section: Methods For Sustainable Energy Production From Biomass Utili...mentioning

confidence: 99%

“…Several studies have assessed the performance of zirconium‐based catalysts in biomass gasification. [ 108 ] These studies evidenced that these catalysts could enhance gasification efficiency and product quality, leading to increased yields of valuable fuels and reduced formation of pollutants such as tar and soot. For instance, Pongratz et al [ 109 ] conducted a study demonstrating that the use of a nickel mesh and zirconia‐based anode in the gasification of wood pellets in a biomass gasifier with solid oxide fuel cells (SOFCs) resulted in an increased yield of syngas and reduced tar content at a temperature of 850 °C.…”

Section: Methods For Sustainable Energy Production From Biomass Utili...mentioning

confidence: 99%

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Multi‐Pathways for Sustainable Fuel Production from Biomass Using Zirconium‐Based Catalysts: A Comprehensive Review

Purnama,

Trisunaryanti,

Wijaya

et al. 2023

Energy Tech

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Numerous concerns, including environmental impact and public health issues, drive the urgent need to replace nonrenewable fossil fuels with renewable energy sources, with biomass emerging as a viable alternative globally. In this comprehensive review, the urgent need to transition from nonrenewable fossil fuels to renewable energy sources is addressed, focusing on biomass as a global alternative. It examines the role of zirconium‐based catalysts in converting biomass into biofuels and hydrogen. Various biomass extraction methods based on the thermochemical processes (pyrolysis, gasification, hydrothermal liquefaction, hydrocracking, and steam reforming) are explored, including their merits and limitations. Additionally, the properties of zirconium‐based catalysts and their catalytic efficiency in biomass conversion are assessed, highlighting the factors influencing their performance. In this literature review, the promising potential of zirconium‐based catalysts in enhancing the sustainability and efficiency of global biofuel production from biomass is revealed. It underscores the critical role of biomass as a renewable energy source and highlights the significance of zirconium‐based catalysts in advancing sustainable biofuel production. It offers insights into addressing environmental concerns, promoting public health, and supporting the global transition toward renewable energy solutions.

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Section: Methods For Sustainable Energy Production From Biomass Utili...mentioning

confidence: 99%

Section: Methods For Sustainable Energy Production From Biomass Utili...mentioning

confidence: 99%

Multi‐Pathways for Sustainable Fuel Production from Biomass Using Zirconium‐Based Catalysts: A Comprehensive Review

Purnama,

Trisunaryanti,

Wijaya

et al. 2023

Energy Tech

View full text Add to dashboard Cite

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“…In particular, the pore characteristic of the reacted catalyst under 1 mL/min H2O steam was better, which was consistent with the analysis of the experimental results. Table 7 listed the related studies on the production of hydrogen-rich gas by the catalytic pyrolysis of biomass in recent years [27][28][29][30][31][32][33][34][35][36][37][38][39][40], in which the catalyst type, type of raw material, gas composition, and yield were taken as indicators. In contrast, in this study, the pyrolysis temperature and flow rate of H2O steam had a great influence on the catalytic pyrolysis law of wood biomass.…”

Section: Enhanced Catalytic Pyrolysis Of Wood Biomass Under H 2 O Ste...mentioning

confidence: 99%

A Study on the Pyrolysis Behavior and Product Evolution of Typical Wood Biomass to Hydrogen-Rich Gas Catalyzed by the Ni-Fe/HZSM-5 Catalyst

Li,

Lu,

Liu

et al. 2024

Catalysts

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The thermo-chemical conversion of biomass wastes is a practical approach for the value-added reclamation of bioenergy in large quantities, and pyrolysis plays a core role in this process. In this work, poplar (PR) and cedar (CR) were used as staple wood biomasses to investigate the apparent kinetics of TG/DTG at different heating rates. Secondly, miscellaneous wood chips (MWC), in which PR and CR were mixed in equal proportion, were subjected to comprehensive investigations on their pyrolysis behavior and product evolution in a fixed bed reactor with pyrolysis temperature, catalyst, and the flow rate H2O steam as influencing factors. The results demonstrated that both PR and CR underwent three consecutive pyrolysis stages, the TG/DTG curves shifted to higher temperatures, and the peak temperature intervals also enhanced as the heating rate increased. The kinetic compensation effect expression and apparent reaction kinetic model of CR and PR pyrolysis were obtained based on the law of mass action and the Arrhenius equation; the reaction kinetic parameter averages of Ea and A of its were almost the same, which were about 72.38 kJ/mol and 72.36 kJ/mol and 1147.11 min−1 and 1144.39 min−1, respectively. The high temperature was beneficial for the promotion of the pyrolysis of biomass, increased pyrolysis gas yield, and reduced tar yield. This process was strengthened in the presence of the catalyst, thus significantly increasing the yield of hydrogen-rich gas to 117.9 mL/g-biomass. It was observed that H2O steam was the most effective activator for providing a hydrogen source for the whole reaction process, promoted the reaction to proceed in the opposite direction of H2O steam participation, and was beneficial to the production of H2 and other hydrocarbons. In particular, when the flow rate of H2O steam was 1 mL/min, the gas yield and hydrogen conversion were 76.94% and 15.90%, and the H2/CO was 2.07. The yields of H2, CO, and CO2 in the gas formation were significantly increased to 107.35 mL/g-biomass, 53.70 mL/g-biomass, and 99.31 mL/g-biomass, respectively. Therefore, H2 was the most dominant species among gas products, followed by C-O bond-containing species, which provides a method for the production of hydrogen-rich gas and also provides ideas for compensating or partially replacing the fossil raw material for hydrogen production.

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“…[18][19][20] However, although signicant progress has been achieved, [19][20][21][22][23][24][25][26] biomass gasication remains at the development stage as there are still challenges for the wide implementation of biomass gasication plants, which are mainly related to feedstock availability and variability, technology efficiency, and cost-effectiveness compared to other energy sources. [27][28][29][30][31] Among others, the variable chemical composition and properties of biomass is one of the main technical and economic challenges to overcome for the commercial deployment of this technology. 20 The broad range of possibilities in gasication processes related to the versatility of the gaseous product, i.e., syngas, raises many practical questions such as "What is the most promising use of a particular type of biomass?…”

Section: Introductionmentioning

confidence: 99%

“…18–20 However, although significant progress has been achieved, 19–26 biomass gasification remains at the development stage as there are still challenges for the wide implementation of biomass gasification plants, which are mainly related to feedstock availability and variability, technology efficiency, and cost-effectiveness compared to other energy sources. 27–31 Among others, the variable chemical composition and properties of biomass is one of the main technical and economic challenges to overcome for the commercial deployment of this technology. 20…”

Section: Introductionmentioning

confidence: 99%

Biomass to energy: a machine learning model for optimum gasification pathways

et al. 2023

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Hydrogen-rich syngas production from the lignocellulosic biomass by catalytic gasification: A state of art review on advance technologies, economic challenges, and future prospectus

Cited by 68 publications

References 123 publications

Multi‐Pathways for Sustainable Fuel Production from Biomass Using Zirconium‐Based Catalysts: A Comprehensive Review

Multi‐Pathways for Sustainable Fuel Production from Biomass Using Zirconium‐Based Catalysts: A Comprehensive Review

A Study on the Pyrolysis Behavior and Product Evolution of Typical Wood Biomass to Hydrogen-Rich Gas Catalyzed by the Ni-Fe/HZSM-5 Catalyst

Biomass to energy: a machine learning model for optimum gasification pathways

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