2016
DOI: 10.1016/j.cherd.2016.01.016
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Hydrogenation of crude terephthalic acid by supported Pd and Pd–Sn catalysts on functionalized multiwall carbon nanotubes

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Cited by 10 publications
(3 citation statements)
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“…4-Methylbenzoic acid was further hydrogenated and sequentially produced 4-methylbenzaldehyde, 4-methylbenzyl alcohol, xylene, and dimethylcyclohexane (Route A). This route is in line with the reaction pathway for TPA hydrogenation over a Pd-based catalyst presented by Tourani et al [42] Differently, the oxygenated ring-hydrogenated products (e. g., cyclohexanecarboxylic acid and cyclohexanedicarboxylic acid) found in earlier studies [39,42] were not observed here. This might be related to the lower hydrogenation activity of the non-noble Co-based catalyst than that of the noble Pd-based ones.…”
Section: Samplesupporting
confidence: 92%
“…4-Methylbenzoic acid was further hydrogenated and sequentially produced 4-methylbenzaldehyde, 4-methylbenzyl alcohol, xylene, and dimethylcyclohexane (Route A). This route is in line with the reaction pathway for TPA hydrogenation over a Pd-based catalyst presented by Tourani et al [42] Differently, the oxygenated ring-hydrogenated products (e. g., cyclohexanecarboxylic acid and cyclohexanedicarboxylic acid) found in earlier studies [39,42] were not observed here. This might be related to the lower hydrogenation activity of the non-noble Co-based catalyst than that of the noble Pd-based ones.…”
Section: Samplesupporting
confidence: 92%
“…A sonochemical treatment procedure oxidized the MWCNTs in a 1:3 (v/v) solution of HNO3 (65%) and H2SO 4 (98%) in an ultrasonic bath maintained at 60 o C for three h. The solution was then diluted in an ice bath for eight h, ltered, and washed under a vacuum using DI water to remove excess acid and solvent until the pH of the ltrate was neutral. The cake was dried in an oven at 60 o C for 24 h [21][22][23].…”
Section: Puri Cation Of Cnt and Oxidation Of Cntmentioning
confidence: 99%
“…Carbon nanotubes (CNTs) containing multiwalled (MWCNTs) and single-walled (SWCNT) structures have excellent chemical [23] and mechanical stability, [24] significant thermal conductivity, [25,26] large surface area, [27] and electrical properties, [28] which make them an ideal and potentially useful choice for applications in electronics, [29] optics, [30] catalysis, [31,32] polymer composites, [33] and many others.…”
Section: Introductionmentioning
confidence: 99%