Hydrogeochemical Characteristics and Groundwater Quality Evaluation Based on Multivariate Statistical Analysis

A combined hydrogeochemical and hydrodynamic characterization for the assessment of key aspects related to groundwater resources management was performed in a highly productive agricultural basin of the Thessaly region in central Greece. A complementary suite of tools and methods—including graphical processing, hydrogeochemical modeling, multivariate statistics and environmental isotopes—have been applied to a comprehensive dataset of physicochemical analyses and water level measurements. Results revealed that the initial hydrogeochemistry of groundwater was progressively impacted by secondary phenomena (e.g., ion exchange and redox reactions) which were clearly delineated into distinct zones according to data processing. The progressive evolution of groundwater was further verified by the variation of the saturation indices of critical minerals. In addition, the combined use of water level measurements delineated the major pathways of groundwater flow. Interestingly, the additional joint assessment of environmental isotopes revealed a new pathway from E–NE (which had never before been validated), thus highlighting the importance of the joint tools/methods application in complex scientific tasks. The application of multivariate statistics identified the dominant processes that control hydrogeochemistry and fit well with identified hydrodynamic mechanisms. These included (as dominant factor) the salinization impact due to the combined use of irrigation water return and evaporitic mineral leaching, as well as the impact of the geogenic calcareous substrate (mainly karstic calcareous formations and dolostones). Secondary factors, acting as processes (e.g., redox and ion exchange), were identified and found to be in line with initial assessment, thus validating the overall characterization. Finally, the outcomes may prove to be valuable in the progression toward sustainable groundwater resources management. The results have provided spatial and temporal information for significant parameters, sources, and processes—which, as a methodological approach, could be adopted in similar cases of other catchments.

Section: Groundwater Sampling Analyses and Measurementsmentioning

confidence: 93%

Section: Stable Isotopesmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Hydrogeochemical and Hydrodynamic Assessment of Tirnavos Basin, Central Greece

Vrouhakis

Tziritis²,

Παναγόπουλος³

et al. 2021

“…Literature studies covered the application of HCA for hydro-geochemical characteristics and groundwater quality evaluation/classification based on sampled data. For example, Chai et al and Liu et al suggested that HCA is a powerful tool for evaluating groundwater pollution and identifying groundwater hydro-geochemical characteristics in China [18,19]. Similarly, HCA has been used for groundwater classification in Southern Ghana [20]; water quality assessment in East Algeria [21]; hydro-geochemical analysis of groundwater in Iran [22] to name a few.…”

Section: Introductionmentioning

confidence: 99%

Characterization of Regional Groundwater System Based on Aquifer Response to Recharge–Discharge Phenomenon and Hierarchical Clustering Analysis

Hussain

Lin

et al. 2021

The investigations of groundwater hydrograph reasonably reflect the aquifer response to recharge–discharge phenomenon and its characteristics. A better understanding of aquifer characteristics such as regional aquifer classification, recharge and discharge patterns, aquifer geology and flow patterns are the surface indicators that may be more effective and less costly for interpreting basic regional hydrogeological conditions and assessments. This study deals with the application of Hierarchical Clustering Analysis to understand the groundwater spatio-temporal patterns and to visualize/classify the nature of the aquifer in the regional area of Kaohsiung City, Taiwan. Groundwater level fluctuation patterns and slopes of rising and recession limbs are used to identify the pumping effects and classify aquifers. The results of clustering analysis show that the groundwater observation wells in the study area can be divided into five major characteristics along with the upstream to downstream of Kaoping River. The clusters are consistent with basic lithology distribution and age of sedimentary, which represents the characteristics of groundwater level fluctuation. The identified groundwater hydrographs patterns provide newer insights related to aquifer response to recharge–discharge phenomenon, types of aquifers and their behaviors. The knowledge of water level fluctuations in the observation wells provides a piece of prior information about the abstraction of groundwater. The proposed aquifer classification and pumping effect have great potential for applied use in groundwater management e.g., save drilling cost.

“…Determination of the distribution function and calculation of the membership degree to construct the fuzzy matrix R [22].…”

mentioning

confidence: 99%

Application of a New Improved Weighting Method, ESO Method Combined with Fuzzy Synthetic Method, in Water Quality Evaluation of Chagan Lake

Zhao

Xiao

Chai

et al. 2021

Self Cite

The existing weighting methods mainly comprise subjective and objective weighting and have a certain degree of subjectivity, with certain requirements for the professional ability of the users and unstable results. Therefore, an improved weighting method based on the entropy weight, over-standard multiple, and single-factor evaluation methods, referred to as the ESO method, is proposed. The advantages and advancements of the ESO method are demonstrated in this study by combining it with the fuzzy synthetic evaluation method to evaluate the water quality of Chagan Lake wetland from 2007 to 2016. The main conclusions of this study are as follows: 1. The ESO method has more comprehensive consideration factors, lower requirements for the professional ability of users, and more stable weighting results than the traditional weighting method. Therefore, it is highly suitable for beginners and frontline staff who are not professionally qualified and cannot accurately conduct subjective weighting. Meanwhile, owing to the amendment rule and emphasis on the local weight of the sample in the ESO method, it is applicable to time-series samples. 2. The ESO method better allocates the amendment weights to indicators with a higher degree of pollution; thus, the final comprehensive evaluation results are relatively conservative. However, in contrast to the single-factor evaluation, the conservatism of ESO method is the result of the comprehensive effect of all samples; thus, the conservative result of the ESO method is more reasonable. 3. The water quality of Chagan Lake in 2009 and 2015 was class IV, which did not meet the standard, while that in remaining the eight years was class III, which met the requirements of the national 13th Five-Year Plan. The results of this study can provide a new approach to weighting calculation methods and a basis for the protection and treatment of the ecological environment of the Chagan Lake wetland.