The chemical and isotopic compositions of river and groundwater reflect the different natural processes that provide chemical elements to the dissolved load, i.e. mainly the weathering of rocks and soils, atmospheric inputs and anthropogenic disturbances.This study reports on the geochemistry of surface-and groundwater along a part of the Subarnarekha River system (north-eastern India) collected during monsoon and dry season, during a monitoring program aimed at evaluating impacts of mining and metallurgy on the river system.The aquifer is of fracture type and the seasonal behaviour, groundwater flow conditions and pollutant transfer were observed through a network of 69 wells with typical depths of 50 meters.Geochemical observations, including major cations and anions, trace element concentrations and isotopic tracing (stable isotopes of the water molecule, strontium isotopes) come to conclusions on the origin and the relationships between the surface-and groundwater in the studied catchment.A large range of salinities is observed in surface-and groundwater, both for dry or wet periods.Surface water samples plot within the field HCO 3 -Ca during both water stages. Most groundwater samples plot within the field of Ca-SO 4 water type and HCO 3 -Ca water type. This reflects the high Ca input in groundwater, other than weathering. Such inputs could be related to (i) carbonate amendments used in agricultural practices and (ii) residues from ore processing.