2017
DOI: 10.1021/acsami.7b08657
|View full text |Cite
|
Sign up to set email alerts
|

Hyper-Cross-Linking Mediated Self-Assembly Strategy To Synthesize Hollow Microporous Organic Nanospheres

Abstract: Hollow microporous organic nanospheres (H-MONs) are prepared by using polylactide-b-polystyrene diblock copolymers (PLA-b-PS) as the precursor via a hyper-cross-linking mediated self-assembly strategy, in which the hyper-cross-linking PS block forms the microporous organic shell framework, and the degradable PLA block produces the hollow mesoporous core structure. The formation mechanism, morphology, and porosity parameters of the resulting H-MONs are systematically investigated. Moreover, based on the hyper-c… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
2
1

Citation Types

4
40
0

Year Published

2018
2018
2021
2021

Publication Types

Select...
6

Relationship

4
2

Authors

Journals

citations
Cited by 43 publications
(44 citation statements)
references
References 51 publications
4
40
0
Order By: Relevance
“…The typical synthesis procedure is shown in Scheme 1. According to our previous work, 30 the HMONs were firstly synthesized by using polylactide-b-polystyrene diblock copolymers (PLA-b-PS) as the precursor via a Friedel-Crafts alkylation reaction with AlCl 3 as catalyst and CCl 4 as the cross-linker and solvent (Supporting Information Fig. S1).…”
Section: Resultsmentioning
confidence: 99%
See 3 more Smart Citations
“…The typical synthesis procedure is shown in Scheme 1. According to our previous work, 30 the HMONs were firstly synthesized by using polylactide-b-polystyrene diblock copolymers (PLA-b-PS) as the precursor via a Friedel-Crafts alkylation reaction with AlCl 3 as catalyst and CCl 4 as the cross-linker and solvent (Supporting Information Fig. S1).…”
Section: Resultsmentioning
confidence: 99%
“…All reagents were used as received unless stated otherwise. HMONs were synthesized according to literature procedures . FT‐IR analysis was carried out using Thermo NICOLET is50.…”
Section: Methodsmentioning
confidence: 99%
See 2 more Smart Citations
“…[24][25][26][27] In this work, we employed ac ovalenta ssembly strategy to fabricater obust and biodegradable nanoarchitectonics through cross-linking with genipin. [28][29][30] Genipin is an atural compound that provides effective cross-linking ability with a very low level of cytotoxicity compared with conventional cross-linking agents (like glutaraldehyde and epoxide), good biocompatibility and biodegradability as wella sd egradation products with non-toxic side effectsa nd ac ross-linking product with ah igh level of stability. [31][32][33][34] The cross-linking can significantly enhancet he rigidity owing to the strong covalent bonding.…”
Section: Introductionmentioning
confidence: 99%