catena-Poly[[trimethyltin(IV)]-μ-2,3-bis(4-chlorophenyl)propenoato-κ²O:O′]

Abstract

metal-organic papers m670 Sadiq-ur-Rehman et al. [Sn(CH 3) 3 (C 15 H 9 Cl 2 O 2)]

Synthesis and coordination chemistry of organotin(IV) complexes of 2,3-methylenedioxyphenylpropenoic acid

“…In this geometry, three methyl groups are equatorial while both oxygens are axial [28]. [35]. Figure 3 shows the molecular structures and atomic numbering scheme of 6.…”

Synthesis, structural elucidation, and biological activity to organotin(IV) derivatives of (E)‐2,3‐bis(4‐chlorophenyl)‐2‐propenoic acid

“…Keeping theses aspects under consideration, in continuation to our previous work, we report here the synthesis and characterization of organotin(IV) derivatives of ( E )‐2,3‐bis(4‐chlorophenyl)‐2‐propenoic acid and their antibacterial, antifungal, and cytotoxicity studies. Cinnamic acid is a naturally occurring unsaturated carboxylic acid that has low toxicity and a broad spectrum of biological activities.…”

“…The IR data play an important role in characterizing organotin(IV) carboxylates. There are two important ways of characterizing organotin(IV) carboxylates: firstly by comparison with that of precursors and then with that of the reported data, and secondly, verification of functional group presence . The coordination of carboxylate group is decided on the basis of the Δν[ν(OCO) asym‐ ν(OCO) sym ] in organotin compounds .…”

“…The characteristic resonance peaks in the 1 H NMR spectra of compounds 1‐8, and free ligand is given in experimental part. The spectra were assigned on the basis of peak intensity, multiplicities, and comparison with the literature values reported earlier …”

“…The biochemical activity of organotin(IV) compounds is based on the structure and coordination number around the tin moiety. [10][11][12] Keeping theses aspects under consideration, in continuation to our previous work [15][16][17][18][19][20][21][22][23][24][25][26] , we report here the synthesis and characterization of organotin(IV) derivatives of (E)-2,3-bis(4-chlorophenyl)-2-propenoic acid and their antibacterial, antifungal, and cytotoxicity studies. Cinnamic acid is a naturally occurring unsaturated carboxylic acid that has low toxicity and a broad spectrum of biological activities.…”