Spin-dependent Kapitza-Dirac scattering of electron beams from counterpropagating bichromatic laser waves in various polarization geometries is studied. The corresponding scattering probabilities are obtained by analytical and numerical solutions of the time-dependent Dirac equation, assuming a field frequency ratio of 2. When the fundamental field mode is circular-polarized, we show that spin dynamics are generally suppressed at low intensities, but can become distinct at high intensities. Conversely, when a linearly or elliptically polarized fundamental mode is combined with a second harmonic of circular polarization, strong spin effects arise already at low field intensities. In particular, a polarization configuration is identified which acts as a spin filter for free electrons.