Key indicators: single-crystal X-ray study; T = 153 K; mean (C-C) = 0.002 Å; R factor = 0.032; wR factor = 0.073; data-to-parameter ratio = 27.9.In the title compound, C 11 H 13 BrOS, the thioether unit and the phenyl ring adopt an essentially planar conformation, with a maximum deviation of 0.063 Å . In the crystal, molecules are linked by C-HÁ Á ÁO hydrogen bonds, extending in zigzag chains along the b axis. A weak intramolecular C-HÁ Á ÁBr hydrogen bond is also observed, which forms an S(6) ring motif.
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