N-(4-Chlorophenyl)-1,1,1-trifluoro-N-(trifluoromethylsulfonyl)methanesulfonamide

Abstract

The title mol­ecule, also called 4-chloro-N,N-bis­(trifluoro­methane­sulfon­yl)aniline, C8H4ClF6NO4S2, has non-crystallographic twofold symmetry with the pseudo-axis aligned along the Cl—C⋯C—N backbone of the mol­ecule: the SO2CF3 residues lie to either side of the benzene ring. In the crystal, the presence of C—H⋯O contacts lead to the formation of a sequence of 12-membered {⋯HC2NSO}2 synthons within a supra­molecular chain aligned along [101].

N-(4-Methoxy-2-nitrophenyl)-N-(methylsulfonyl)methanesulfonamide

“…2 and Table 1). The bond lengths and angles are within the normal range and similar to other closley related structures (Boechat et al, 2010;Zia-ur-Rehman et al, 2009).…”

“…For the biological activities of sulfonamides, see: Alsughayer et al (2011); Joshi & Khosla (2003); Scozzafava et al (2003); Drews (2000); Peixoto & Beverley (1987). For crystal structures of closely related compounds, see: Boechat et al (2010); Zia-ur-Rehman et al (2009).…”