“…[14] Ellipsoids are set to 50 %p robability;Hatoms, solvent molecules, anion, and substituents on CAAC for 5b and 7b are omitted for clarity. Selected distances []and angles [8 8]: a) 2b:P1-P2 2.2360 (6), P1-C1 1.623(2), C1-C2 1.324(3);P 2-P1-C1 99.79 (8), P1-C1-C2 173.18(16);b) 5b:P1-P2 2.6846 (6), P1-P3 2.2082 (6), P1-C1 1.8494(18),C 1-P2 1.8577(18), P2-C3 1.8578(18), C3-P1 1.8412(18),P 2-C5 1.8828(18), P3-C5 1.8040(18), C1-C2 1.357(2), C3-C4 1.352(2), C5-C6 1.386(2); C5-P3-P1 94.40 (6), P3-P1-C3 94.15 (6), P3-P1-C1 91.61 (6);c )6e:P 1-P1' 2.2508 (8), P1-C1 1.6336(17),C 1-C2 1.324(2);P 1 '-P1-C1 99.30 (7), P1-C1-C2 175.67 (14);d)7b:P 1-P2 2.755, P1-P3 2.2252 (7), P1-C1 1.939(2), C1-P2 1.941(2), P2-C3 1.837(2), C3-P1 1.910(2), P2-C5 1.856(2), P3-C1 1.808(2), P3-C5 1.821(2), C1-C2 1.443(3), C3-C4 1.365(3), C5-C6 1.371(3);C 5-P3-P1 84.05 (9), C5-P3-C1 84.05 (9), P3-P1-C3 99.22 (7), P3-P1-C1 54.09 (6).…”