trans-Dichloro(2-chloroaniline-κN)(triphenylphosphine-κP)palladium(II) dichloromethane solvate

Abstract

Key indicatorsSingle-crystal X-ray study T = 298 K Mean (C-C) = 0.006 Å R factor = 0.044 wR factor = 0.116 Data-to-parameter ratio = 21.0 For details of how these key indicators were automatically derived from the article, see

Dichlorido(4-methylaniline-κN)[N-(4-methylphenyl)-1-(thiophen-2-yl)methanimine-κN]palladium(II)

“…In addition, the coordination plane (Pd1, Cl1, Cl2, N1, and N2) is almost perpendicular to both the planes of the coordinated o-toluidine ring and the C5, C6, N1 fragment [dihedral angles of 84.7 (1) and 72.50 (4) , respectively]. A search of the CSD (Groom et al, 2016) for structures containing a Pd(NH 2 -phenyl derivative)Cl 2 fragment contained 90 observations of the Pd-NH 2 bond with a mean value of 2.065 (35) A ˚and minimum and maximum values of 2.028 A ˚(Baldovino-Pantaleo ´n et al, 2007) and 2.171 A ˚ (Asma et al, 2005), respectively. Thus, the length of 2.040 (2) A ˚in the title compound is slightly shorter than the observed mean value.…”

Synthesis, Characterization of Mixed Ligand Palladium(II) Complexes of Triphenylphosphine and Anilines and their Enzyme Inhibition Studies against β-glucuronidase. The Crystal Structure of trans-dichloro-(m-chloroaniline)(triphenylphosphine)palladium(II)

“…The X-ray structure of one of the complexes, [(Ph 3 P)Pd(m-Cl NH 2 C 6 H 4 )Cl 2 ]AECH 2 Cl 2 is also reported. Recently, we have reported the crystal structure of analogous complexes, dichloro(dicyclohexylamine)(triphenylphosphine) palladium(II) and trans-dichloro(2-chloroaniline-kN) triphenylphosphine-kP)palladium(II) dichloromethane solvate [18,19]. The complexes were found to be active inhibitors against the activity of the enzyme b-glucuronidase.…”