“…Numerous methods have been developed to investigate how temperature affects the EXAFS cumulants, such as path-integral effective-potential theory (Yokoyama, 1999), the statistical moment method (V. v. Hung et al, 2010), the ratio method (Bunker, 1983), the Debye model (Beni & Platzman, 1976), the Einstein model (Frenkel & Rehr, 1993), and the anharmonic correlated Einstein model (ACEM) (N. v. Hung & Rehr, 1997). Several groups have applied ACEM theory to EXAFS to study how the thermodynamic properties depend on temperature with the effect of the material doping ratio (DR) (Duc et al, 2017;Hung et al, 2015;Kraut & Stern, 2000;Nafi et al, 2013). However, no reports to date have discussed how the thermodynamic parameters and the Debye-Waller factor (DWF) depend on temperature and pressure for Cu, Ag, and their intermetallic alloy CuAg72.…”