2020
DOI: 10.1103/physrevlett.125.033001
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Identification of Dy3+/Dy2+ as Electron Trap in Persistent Phosphors

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Cited by 84 publications
(81 citation statements)
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“…After crossing a thermal barrier, the electron can eventually be trapped at a meta‐stable “trap” level in the band gap (created by, e.g., oxygen vacancies or co‐dopants). [ 61–64 ] With BaSiON now in a charged state (filled electron traps), delayed emission can occur when external energy is supplied to the phosphor. This energy can be the result of electromagnetic radiation, heat, electric fields, etc.…”
Section: Resultsmentioning
confidence: 99%
“…After crossing a thermal barrier, the electron can eventually be trapped at a meta‐stable “trap” level in the band gap (created by, e.g., oxygen vacancies or co‐dopants). [ 61–64 ] With BaSiON now in a charged state (filled electron traps), delayed emission can occur when external energy is supplied to the phosphor. This energy can be the result of electromagnetic radiation, heat, electric fields, etc.…”
Section: Resultsmentioning
confidence: 99%
“…Thus, the divalent energy level positions related to the conduction band would determine the amount of thermal energy needed for depopulating the traps. Recently, Joos and co-workers [ 159 ] investigated the Sr 2 MgSi 2 O 7 :Eu 2+ , Dy 3+ material and identified the reversible Dy 3+ reduction during irradiation combining laser excitation and X-ray spectroscopy, proving that co-dopants act also as electron traps. This trapping property of the RE 3+ co-dopants is efficient only when the energy level of the correspondent RE 2+ ion is below the conduction band with appropriate energy.…”
Section: Persistent Luminescencementioning
confidence: 99%
“…Since its discovery in 1996 [3] many different models for the afterglow mechanism have been proposed. [5][6][7][8][9] Despite extensive research of many scientists, so far none of the proposed mechanisms can explain all experimental findings of the last 25 years, and the true mechanism remains to be found. It is mostly agreed upon that under illumination of the materials, electrons from the excited europium ions are transferred to and caught in different so-called trap-states.…”
Section: Swiss Super-luminova ®mentioning
confidence: 99%