Mixtures of poly(carbon monofluoride) also known as graphite fluoride, (CF)n, with different reductants, such as NaN3, B, Ti, ZrTi, Si, CaSi2, AlSi, TiSi, MoSi2 and CrSi2 were investigated. Reactions between these substrates are fast and exothermic enough to proceed in a high temperature, self‐sustaining regime. Heat effects accompanying the reactions were measured and the solid reaction products were analyzed. SEM observation revealed the presence of exfoliated graphite in each case. Nanostructures, like nanofibers, nanorods, nanospheres and nanosized crystals, were also present in most of the products. Phase (XRD) and elemental composition as well as porous structure (N2 adsorption) of chosen reaction products were also determined.