2002
DOI: 10.1016/s0960-8524(01)00203-6
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Immobilized Candida antarctica lipase-catalyzed alcoholysis of cotton seed oil in a solvent-free medium

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Cited by 250 publications
(17 citation statements)
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“…This behavior could be explained by the alcohol inhibition effect [77], [78], [79]. Due to high polarity of short-chain alcohols, such as ethanol, the alcohol can be adsorbed on the carrier on which the enzyme was immobilized, removing the layer of hydration of the enzyme, which can promote its inactivation [58].
Fig. 5Panel (A): Influence of molar ratio alcohol: acid in the enzymatic esterification of oleic acid with ethanol by means of supercritical fluid at a temperature of 35 °C.
…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…This behavior could be explained by the alcohol inhibition effect [77], [78], [79]. Due to high polarity of short-chain alcohols, such as ethanol, the alcohol can be adsorbed on the carrier on which the enzyme was immobilized, removing the layer of hydration of the enzyme, which can promote its inactivation [58].
Fig. 5Panel (A): Influence of molar ratio alcohol: acid in the enzymatic esterification of oleic acid with ethanol by means of supercritical fluid at a temperature of 35 °C.
…”
Section: Resultsmentioning
confidence: 99%
“…The variables and their levels were selected based on the literature [58], [59], [60], [61], as it could be observed in Table 1.…”
Section: Methodsmentioning
confidence: 99%
“…Köse and coworkers [86] investigated lipase-catalyzed transesterification of cotton seed oil with methanol in solvent-free medium. Yield of 92% was achieved in the presence of the Novozym 435 in 24 h reaction.…”
Section: Biodieselmentioning
confidence: 99%
“…Of the genus Pseudozyma , P. antarctica was initially isolated on the bottom of a lake in Antarctica as Candida antarctica , and found to produce industry-relevant extracellular lipases at high levels. Their modification was thoroughly investigated to enhance the efficiency of the reaction and expand their industrial application [7], [8], [9]. Very recently, the extracellular production of an excellent biodegradable plastic–degrading enzyme, which degrades poly-butylene succinate and poly-butylene succinate-co-adipate, was found in the strains of P. antarctica isolated from plant surfaces [10].…”
Section: Introductionmentioning
confidence: 99%