In this study, a post-weld heat treatment (PWHT) was proposed at high temperatures of 600 °C, 750 °C, and 900 °C for 30 min to significantly improve the impact absorbed energy of high manganese steel weld metal. Electron backscatter diffraction (EBSD), electron probe microanalysis (EPMA), and high-angle annular dark field scanning transmission electron microscopy (HAADF-STEM) were employed to characterize the production and study the deformation mechanisms in the high manganese steel weld metal. The impact absorbed energy is divided into crack initiation energy and crack propagation energy, which are divided by the value of Pmax. The cryogenic impact absorbed energy was 81 J. After PWHT at 600 °C, 750 °C, and 900 °C, it was 75 J, 69 J, and 88 J, respectively. The impact absorbed energies did not follow a proportional relationship with the PWHT temperatures. The increase in impact absorbed energy can be attributed to the narrowing of the dendritic region, which blocks the crack propagation path and efficiently prevents crack propagation. Conversely, the decrease in impact absorbed energy can be attributed to the presence of 100-nm-sized (Cr, Mn)23C6-type carbides at the grain boundaries, which facilitate crack propagation.