Impact of climatic and soil conditions on environmental fate of atrazine used under plantation forestry in Australia

Kookana, Rai S.; Holz, Greg; Barnes, Chris; Bubb, Ken; Fremlin, R. R. A.; Boardman, B. Tom

doi:10.1016/j.jenvman.2010.07.037

Cited by 38 publications

(23 citation statements)

References 26 publications

Supporting

Mentioning

Contrasting

Unclassified

Order By: Relevance

“…The HA peak would be observed close to the peaks of DIA and DEA and before the AT peak, 5,17,27 but this was not observed. HA has a strong interaction with soil particles with high sorption coefficient, 2,5,8 and might be considered as a bound residue, 3,8 requiring the use of more vigorous extraction processes. Furthermore, the solubility of HA in water is close to 7.0 mg L −1 , 2 that could minimize its extraction.…”

Section: Application Of the Methodsmentioning

confidence: 99%

“…On the other hand, Kleinschmitt et al, 30 employed 24 h as extraction time using pure methanol and verified between 30 and 35% of recovery for AT. Kookana et al, 8 used ACN:water (90:10) and shaking extraction (2 h) for AT, from different soil samples, and showed recovery of 106%. Barchanska et al, 17 reported an extraction study employing a mixture of 0.1 mol L −1 ACN:HCl (90:10), using only 30 min of shaking, before the use of SPE preconcentration.…”

Section: Optimization Of the Shaking Extraction (Se)mentioning

confidence: 99%

“…5 HA presents lower mobility in soils in comparison with DEA and DIA, and for this reason greater attention has been given to these two metabolites and the parent herbicide. [6][7][8][9] According to Potter et al, 6 the monitoring of shallow groundwater in four corn crops in Florida State, USA showed that DEA, DIA and the parent herbicide are the main residues, with DEA accounting for more than half of all residues in most samples. Because of the great importance of this subject, regression models were developed to evaluate groundwater in agricultural areas of USA for AT and DEA, using 1298 wells and explanatory variables related to the source of AT and other aspects of transport and fate of these contaminants in the subsurface.…”

Section: Introductionmentioning

confidence: 99%

“…For these reasons, high performance liquid chromatography (HPLC) has been the analytical technique most largely employed for triazines determination in soils. [1][2][3]5,8,11,[13][14][15][16][17] The quality of the analytical data is mostly dependent on the sample preparation, especially for the procedures of extraction and cleanup, 18 and as a result, this is a critical step for the determination of any contaminant in soil samples. For that reason, several different approaches have been proposed for the extraction and cleanup of triazines in soils.…”

Section: Introductionmentioning

confidence: 99%

“…12,19 Because of this, green extraction methods have been proposed, including ultrasonic solvent extraction (USE), 14,19 microwave assisted extraction (MAE), 15,16 supercritical fluid extraction (SFE), 20 extraction of the analytes after the shaking of the sample in the presence of an appropriate solvent, followed by solid phase extraction (SPE), 17 headspace solid-phase microextraction (HS-SPME), 21 pressurized liquid extraction (PLE), 1,12,13,22 besides the development of other miniaturized methods as reported in the literature. 14 These methods usually present appropriate results, however some authors have used a less expensive extraction method, based on a simple shaking with solvents of adequate polarity like acetonitrile or methanol and water, providing acceptable recovery values for the extraction of triazine herbicides from soils; 5,8,19 nevertheless, the extraction time is often a drawback, for instance, Mahía et al, 5 and Delgado-Moreno et al, 19 employed 24 h as extraction time. As a result, chemometric studies have been used in order to save time and improve the correlation of the different factors involved in the extraction step for triazines and other pesticides.…”

Section: Introductionmentioning

confidence: 99%

See 4 more Smart Citations

Extraction method for the determination of atrazine, deethylatrazine, and deisopropylatrazine in agricultural soil using factorial design

Amadori¹,

Cordeiro²,

Rebouças³

et al. 2013

J. Braz. Chem. Soc.

View full text Add to dashboard Cite

Neste trabalho foi proposto um procedimento para a extração do herbicida atrazina (AT) e dos principais metabólitos desetil-atrazina (DEA) e desisopropil-atrazina (DIA) de uma amostra de latossolo vermelho proveniente da região sudoeste do estado do Paraná no Brasil, onde a AT está entre os herbicidas mais amplamente utilizados. Foi conduzida uma comparação usando extração por agitação e por ultrassom, sendo obtido um procedimento de extração simples e rápido, seguido pela quantificação por cromatografia em fase líquida de alta eficiência. Cabe ressaltar que foi utilizado um estudo por planejamento fatorial, o qual foi decisivo para determinar as melhores condições de extração por agitação. Foram obtidos percentuais de recuperação e desvios padrão relativos adequados, para amostras de solo de três diferentes profundidades, o que sugere a possibilidade de empregar o método de extração proposto para a quantificação de AT, DEA e DIA em amostras de latossolo vermelho.An optimization procedure for the extraction of the herbicide atrazine (AT), and the main degradation products deethylatrazine (DEA) and deisopropylatrazine (DIA) from an oxisol soil sample was carried out, for a soil from the Southwest of Paraná State in Brazil, where AT is among the most largely employed herbicide. A comparison between shaking and ultrasound extraction was performed, to define a simple and fast extraction procedure, followed by the quantification using high performance liquid chromatography. It is important to inform that a factorial planning was employed, that was very important to define the best conditions of extraction by shaking. Appropriate recovery values were observed using soil samples from three different depths, as well as the relative standard deviation, suggesting the possibility to employ the proposed extraction method for quantification of AT, DEA and DIA in oxisol samples.

show abstract

Section: Application Of the Methodsmentioning

confidence: 99%

Section: Optimization Of the Shaking Extraction (Se)mentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 3 more Smart Citations

Extraction method for the determination of atrazine, deethylatrazine, and deisopropylatrazine in agricultural soil using factorial design

Amadori¹,

Cordeiro²,

Rebouças³

et al. 2013

J. Braz. Chem. Soc.

View full text Add to dashboard Cite

show abstract

A study on the correlation of anthropogenic activities with climate change

Mukherjee

Keswani

Nath

et al. 2023

Environmental Quality Mgmt

View full text Add to dashboard Cite

The introduction of dangerous substances known as pollutants that impair the environment is referred to as pollution. It includes major factors like pollutants of the air, water, soil, and minor factors like high decibel noise and plastics—all of which impact human health and well‐being. Pollution is caused by variety of factors, including toxic chemicals released into the water by manufacturers, dangerous gases produced by different factories into the air, and various human activities like ore mining and ore purification. These most often lead to global warming which results in shifting weather and temperature patterns. Pesticides are another significant contributor to both soil and water contamination. These pollutants have emerged as one of the main factors influencing our climate. Their manufacture leads to emission of greenhouse gases which affects the climate of a place. Because of the overuse of pesticides, both the land and the groundwater are contaminated. By impacting the soil, the overall growth, yield and life of the plants are being affected. When introduced into water bodies, pesticides have an impact on the aquatic ecology because the buildup of these dangerous pollutants, which have a higher pH value and also contain toxic metals, which could be detrimental for the aquatic ecosystem. The synergistic impact of various pollutants on environment, climate due to anthropogenic causes, as well as the possible remediation strategies is discussed in this study.

show abstract

Impact of Climate Variability on the Use and Exposure of Pesticides in Sugarcane Production in Malawi

Donga

Meadow

Sitaula

et al. 2020

Climate Impacts on Agricultural and Natural Resource Sustainability in Africa

View full text Add to dashboard Cite

Impact of climatic and soil conditions on environmental fate of atrazine used under plantation forestry in Australia

Cited by 38 publications

References 26 publications

Extraction method for the determination of atrazine, deethylatrazine, and deisopropylatrazine in agricultural soil using factorial design

Extraction method for the determination of atrazine, deethylatrazine, and deisopropylatrazine in agricultural soil using factorial design

A study on the correlation of anthropogenic activities with climate change

Impact of Climate Variability on the Use and Exposure of Pesticides in Sugarcane Production in Malawi

Contact Info

Product

Resources

About