The turbulent combustion flow modeling are performed to study the impacts of CO 2 addition to the fuel and oxidizer streams on the thermochemical characteristics of a swirl stabilized diffusion flame SM1. A flamelet approach along with three well-known turbulence models are utilized to model the turbulent combustion flow field. The k−ω SST shows the best agreement with the experimental fields compared to other methods. Then, the k−ω SST is employed to study the effects of CO 2 dilution on the flame structure and strength, temperature distribution, and CO concentration. To determine the chemical effects of CO 2 dilution, a fictitious species is replaced with the regular CO 2 in both fuel and oxidizer streams.The results indicate that the flame temperature is decreased when CO 2 is added to either fuel or oxidizer streams. The flame length reduction is observed at all levels of CO 2 dilution. The H radical concentration indicating the flame strength decreases following by the thermochemical effects of CO 2 dilution processes. In comparison with fictitious species dilution, chemical effects of CO 2 addition enhance CO mass fraction. The numerical simulations show that by increasing the