The carry‐outs of Dufour and Soret, as well as radiation, and chemical response on a non‐Newtonian MHD Williamson nanofluid flow through an inclined extended plane are discussed in this article. Keller‐box analysis is being used to explore the influence of the Williamson factor here on the fluid domain quantitatively. Ordinary differential equations (ODEs) are recovered from boundary flow equations using appropriate similarity transformations. These ODEs are numerically addressed. Graphs and comparisons are used to simulate and study the features of flow characteristics such as velocity, temperature, and concentration of Williamson nanofluids distributions in response to various emerging parameters. The numerical computations show that our results are in reasonable harmony with previous studies. The numerical computations revealed that for the time being, the density of the momentum fluid layers is diminishing for the values of ᴦ $ᴦ$, Le, Ω $\Omega $, M, and increasing for Gc, Gr. The thickness of the thermal boundary layer is decreasing for Sr, Df, Pr, Gc, and Gr. M, ᴦ $ᴦ$, Ω $\Omega $, R, N, and Le are all on the rise. The concentration profile for R, Le, Nb, Nt, Gr, Gc, and N is decreasing, while Pr, Df, Sr, M, ᴦ $ᴦ$, and Ω $\Omega $ are increasing.